glucose andglucuronic acid. Its viscosity behavior was investigated by a low-shear-rate multiball viscometer and arotational viscometer. Its weight-average molecular weight Mw and intrinsic viscosity [η] in 0.2 mol/L NaClaqueous solution were measured by light scattering method at 35℃ and viscometry at 25℃ and found to be1.06×106 g/mol and 1050 mL/g
respectively
and its aggregates in aqueous solution were proved by gel permeation chromatography (GPC).These results indicated that E gum in water has exceedingly high viscosity and exhibiys Binham fluid behavior
owing to its aggregation.The viscosity of E gum decreased with increasing temperature
and the turning point appeared at 38℃ for dilute solution and 80℃ for concentrated solution suggesting that the affregates of E gum in water started to disaggregate under these temperatures.In addition
the aggregates can be disrupted by adding either acid or base.The experimental results indicated that the E gum is a good thickening agent
and its fluid behavior is similar to xanthan.
Abstract
Erwinia (E) gum
an extracellular polysaccharide
is composed of fucose
galatose
glucose andglucuronic acid. Its viscosity behavior was investigated by a low-shear-rate multiball viscometer and arotational viscometer. Its weight-average molecular weight Mw and intrinsic viscosity [η] in 0.2 mol/L NaClaqueous solution were measured by light scattering method at 35℃ and viscometry at 25℃ and found to be1.06×106 g/mol and 1050 mL/g
respectively
and its aggregates in aqueous solution were proved by gel permeation chromatography (GPC).These results indicated that E gum in water has exceedingly high viscosity and exhibiys Binham fluid behavior
owing to its aggregation.The viscosity of E gum decreased with increasing temperature
and the turning point appeared at 38℃ for dilute solution and 80℃ for concentrated solution suggesting that the affregates of E gum in water started to disaggregate under these temperatures.In addition
the aggregates can be disrupted by adding either acid or base.The experimental results indicated that the E gum is a good thickening agent
and its fluid behavior is similar to xanthan.
关键词
Keywords
references
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