PHOTOPOLYMERIZATION OF MMA INITIATED BY CYANINE DYE AND HEXAARYLBIIMIDAZ0LE*
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PHOTOPOLYMERIZATION OF MMA INITIATED BY CYANINE DYE AND HEXAARYLBIIMIDAZ0LE*
PHOTOPOLYMERIZATION OF MMA INITIATED BY CYANINE DYE AND HEXAARYLBIIMIDAZ0LE*
高分子科学(英文版)1998年16卷第4期 页码:310-315
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纸质出版:1998-12-20
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ZHAO Chunying, YANG Yongyuan, LI Lidong, 等. PHOTOPOLYMERIZATION OF MMA INITIATED BY CYANINE DYE AND HEXAARYLBIIMIDAZ0LE*[J]. 高分子科学(英文版), 1998,16(4):310-315.
ZHAO Chunying, YANG Yongyuan, LI Lidong, et al. PHOTOPOLYMERIZATION OF MMA INITIATED BY CYANINE DYE AND HEXAARYLBIIMIDAZ0LE*[J]. 1998, 16(4): 310-315.
ZHAO Chunying, YANG Yongyuan, LI Lidong, 等. PHOTOPOLYMERIZATION OF MMA INITIATED BY CYANINE DYE AND HEXAARYLBIIMIDAZ0LE*[J]. 高分子科学(英文版), 1998,16(4):310-315.DOI:
ZHAO Chunying, YANG Yongyuan, LI Lidong, et al. PHOTOPOLYMERIZATION OF MMA INITIATED BY CYANINE DYE AND HEXAARYLBIIMIDAZ0LE*[J]. 1998, 16(4): 310-315.DOI:
PHOTOPOLYMERIZATION OF MMA INITIATED BY CYANINE DYE AND HEXAARYLBIIMIDAZ0LE*
The photoinitiating system composed of 1-ethyl-3'-methylthiacyanine bro-mide (C-I)
2-chlorohexaarylbiimidazole (o-Cl-HABI) and 3-mercapto-4-methyl-4H-1
2
4-triazole (MTA)
which act as sensitizer
initiator and hydrogen-donor respectively
can beused to initiate the polymerization of methyl methacrylate (MMA). The kinetic study wascarried out in trichloromathane solution at 30℃ by using dilatometry. The relation be-tween the polymerization rate and the concentrations of C-I
o-Cl-HABI
MTA and MMA was studied.
Abstract
The photoinitiating system composed of 1-ethyl-3'-methylthiacyanine bro-mide (C-I)
2-chlorohexaarylbiimidazole (o-Cl-HABI) and 3-mercapto-4-methyl-4H-1
2
4-triazole (MTA)
which act as sensitizer
initiator and hydrogen-donor respectively
can beused to initiate the polymerization of methyl methacrylate (MMA). The kinetic study wascarried out in trichloromathane solution at 30℃ by using dilatometry. The relation be-tween the polymerization rate and the concentrations of C-I
o-Cl-HABI
MTA and MMA was studied.
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