A NOVEL SUPRAMOLECULAR CLATHRATE OF RODLIKE p-BUTOXYBENZYLIDENE-p′-DODECOXYANILINE TRAPPED WITHIN POLYORGANOSILOXANE PORE*
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A NOVEL SUPRAMOLECULAR CLATHRATE OF RODLIKE p-BUTOXYBENZYLIDENE-p′-DODECOXYANILINE TRAPPED WITHIN POLYORGANOSILOXANE PORE*
A NOVEL SUPRAMOLECULAR CLATHRATE OF RODLIKE p-BUTOXYBENZYLIDENE-p′-DODECOXYANILINE TRAPPED WITHIN POLYORGANOSILOXANE PORE*
高分子科学(英文版)1998年16卷第3期 页码:253-260
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纸质出版:1998-09-20
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XU Hui, CAO Xinyu, LI Ze, 等. A NOVEL SUPRAMOLECULAR CLATHRATE OF RODLIKE p-BUTOXYBENZYLIDENE-p′-DODECOXYANILINE TRAPPED WITHIN POLYORGANOSILOXANE PORE*[J]. 高分子科学(英文版), 1998,16(3):253-260.
XU Hui, CAO Xinyu, LI Ze, et al. A NOVEL SUPRAMOLECULAR CLATHRATE OF RODLIKE p-BUTOXYBENZYLIDENE-p′-DODECOXYANILINE TRAPPED WITHIN POLYORGANOSILOXANE PORE*[J]. 1998, 16(3): 253-260.
XU Hui, CAO Xinyu, LI Ze, 等. A NOVEL SUPRAMOLECULAR CLATHRATE OF RODLIKE p-BUTOXYBENZYLIDENE-p′-DODECOXYANILINE TRAPPED WITHIN POLYORGANOSILOXANE PORE*[J]. 高分子科学(英文版), 1998,16(3):253-260.DOI:
XU Hui, CAO Xinyu, LI Ze, et al. A NOVEL SUPRAMOLECULAR CLATHRATE OF RODLIKE p-BUTOXYBENZYLIDENE-p′-DODECOXYANILINE TRAPPED WITHIN POLYORGANOSILOXANE PORE*[J]. 1998, 16(3): 253-260.DOI:
A NOVEL SUPRAMOLECULAR CLATHRATE OF RODLIKE p-BUTOXYBENZYLIDENE-p′-DODECOXYANILINE TRAPPED WITHIN POLYORGANOSILOXANE PORE*
has been preparedby in-situ encapsulating rodlike p-butoxybenzylidene-p ' - dodecoxyaniline (BBDA )
one kindof Schiff base liquid crystal molecule
within the pore of polyorganosiloxane (POS) whichis prepared by hydrosilylation coupling reaction of polyvinylsilsesquioxane (Vi- T ) withtetramethyldisiloxane (H-MM). Investigation by polarized light microscopy (PLM)
differ-ential scanning calorimetry (DSC)
infrared spectroscopy (IR)
atomic force microscopy (AFM) and molecular simulation gives a preliminary support to the existence of the title supramolecular clathrate.
Abstract
A novel supramolecular polysiloxane clathrate
POS/C
has been preparedby in-situ encapsulating rodlike p-butoxybenzylidene-p ' - dodecoxyaniline (BBDA )
one kindof Schiff base liquid crystal molecule
within the pore of polyorganosiloxane (POS) whichis prepared by hydrosilylation coupling reaction of polyvinylsilsesquioxane (Vi- T ) withtetramethyldisiloxane (H-MM). Investigation by polarized light microscopy (PLM)
differ-ential scanning calorimetry (DSC)
infrared spectroscopy (IR)
atomic force microscopy (AFM) and molecular simulation gives a preliminary support to the existence of the title supramolecular clathrate.
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