PREPARATION AND CATALYTIC BEHAVIOUR OF POLYMER-BOUND METALLOPORPHYRIN IN HYDROGENATION OF OLEFIN

WANG Rongmin; HE Yufeng; LEI Ziqiang; WANG Yunpu; LI Shuben

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PREPARATION AND CATALYTIC BEHAVIOUR OF POLYMER-BOUND METALLOPORPHYRIN IN HYDROGENATION OF OLEFIN

Papers | Updated：2021-06-21

- PREPARATION AND CATALYTIC BEHAVIOUR OF POLYMER-BOUND METALLOPORPHYRIN IN HYDROGENATION OF OLEFIN
- PREPARATION AND CATALYTIC BEHAVIOUR OF POLYMER-BOUND METALLOPORPHYRIN IN HYDROGENATION OF OLEFIN
- 高分子科学（英文版） 1998年16卷第1期页码：91-96
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- 纸质出版：1998-03-20
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WANG Rongmin, HE Yufeng, LEI Ziqiang, 等. PREPARATION AND CATALYTIC BEHAVIOUR OF POLYMER-BOUND METALLOPORPHYRIN IN HYDROGENATION OF OLEFIN[J]. 高分子科学（英文版）, 1998,16(1):91-96.

WANG Rongmin, HE Yufeng, LEI Ziqiang, et al. PREPARATION AND CATALYTIC BEHAVIOUR OF POLYMER-BOUND METALLOPORPHYRIN IN HYDROGENATION OF OLEFIN[J]. 1998, 16(1): 91-96.
WANG Rongmin, HE Yufeng, LEI Ziqiang, 等. PREPARATION AND CATALYTIC BEHAVIOUR OF POLYMER-BOUND METALLOPORPHYRIN IN HYDROGENATION OF OLEFIN[J]. 高分子科学（英文版）, 1998,16(1):91-96. DOI：

WANG Rongmin, HE Yufeng, LEI Ziqiang, et al. PREPARATION AND CATALYTIC BEHAVIOUR OF POLYMER-BOUND METALLOPORPHYRIN IN HYDROGENATION OF OLEFIN[J]. 1998, 16(1): 91-96. DOI：

摘要

The meso- tetraarylporphyrin has been anchored to styrene- divinylbenzenecopolymers by reaction of meso- tetra (4-hydroxylphenyl ) porphyrin with chloromethylatedresin under mild condition. A number of polymer transition metal complexes have beenprepared with the polymer ligand and metal salts. The polymeric ligand and its complexeshave been characterized by electronic spectra

and vibrational spectra. Cyclohexene can behydrogenated with the polymeric porphyrin palladium complex(P-THPPPd) as catalyst

and its catalytic activity was influenced by the polarity of solvents

the contents of water in ethanol or reaction temperature.However

its catalytic activity was lower for intro groups

carbonyl groups and olefins with steric hindrance substityents

and showed no activity for aromatic rings under these conditions.

Abstract

and vibrational spectra. Cyclohexene can behydrogenated with the polymeric porphyrin palladium complex(P-THPPPd) as catalyst

and its catalytic activity was influenced by the polarity of solvents

the contents of water in ethanol or reaction temperature.However

its catalytic activity was lower for intro groups

carbonyl groups and olefins with steric hindrance substityents

and showed no activity for aromatic rings under these conditions.

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