PHOTO-INDUCED DOPED POLYANILINE BY THE VINYLIDENE CHLORIDE AND METHYL ACRYLATE COPOLYMER AS PHOTO ACID GENERATOR*

LI Suzhen; WAN Meixiang

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PHOTO-INDUCED DOPED POLYANILINE BY THE VINYLIDENE CHLORIDE AND METHYL ACRYLATE COPOLYMER AS PHOTO ACID GENERATOR*

Papers | Updated：2021-06-21

- PHOTO-INDUCED DOPED POLYANILINE BY THE VINYLIDENE CHLORIDE AND METHYL ACRYLATE COPOLYMER AS PHOTO ACID GENERATOR*
- PHOTO-INDUCED DOPED POLYANILINE BY THE VINYLIDENE CHLORIDE AND METHYL ACRYLATE COPOLYMER AS PHOTO ACID GENERATOR*
- 高分子科学（英文版） 1997年15卷第2期页码：108-113
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- 纸质出版：1997-06-20
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LI Suzhen, WAN Meixiang. PHOTO-INDUCED DOPED POLYANILINE BY THE VINYLIDENE CHLORIDE AND METHYL ACRYLATE COPOLYMER AS PHOTO ACID GENERATOR*[J]. 高分子科学（英文版）, 1997,15(2):108-113.

LI Suzhen, WAN Meixiang. PHOTO-INDUCED DOPED POLYANILINE BY THE VINYLIDENE CHLORIDE AND METHYL ACRYLATE COPOLYMER AS PHOTO ACID GENERATOR*[J]. 1997, 15(2): 108-113.
LI Suzhen, WAN Meixiang. PHOTO-INDUCED DOPED POLYANILINE BY THE VINYLIDENE CHLORIDE AND METHYL ACRYLATE COPOLYMER AS PHOTO ACID GENERATOR*[J]. 高分子科学（英文版）, 1997,15(2):108-113. DOI：

LI Suzhen, WAN Meixiang. PHOTO-INDUCED DOPED POLYANILINE BY THE VINYLIDENE CHLORIDE AND METHYL ACRYLATE COPOLYMER AS PHOTO ACID GENERATOR*[J]. 1997, 15(2): 108-113. DOI：

摘要

The emeraldine base form of polyaniline (PANI) can be doped by a photo-induceddoping method. In this method a copolymer of vinylidene chloride and methyl acrylate(VCMAC) was used as photo acid generator which can release proton when it is exposedto ultraviolet light (λ= 254 nm). The structure of PANI-VCMAC system before and afterirradiation was characterized by elemental analysis

XPS

and SEM images. Resultsobtained indicate that the photo-induced doping characteristics

such as doping position and type of charge carriers

are similar to that of PANI doped with HCl.The poor room-temperature conductivity (～10-5S/cm) of PANI-VCMAC system after irradiation may be due to low doping degree (～pH=3)and the difference in morphology as compared with PANI-HCl film.

Abstract

XPS

and SEM images. Resultsobtained indicate that the photo-induced doping characteristics

such as doping position and type of charge carriers

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