SYNTHESIS OF POLYSILOXANE-SUPPORTED SELENAETHER PLATINUM COMPLEX AND ITS CATALYTIC PROPERTY FOR HYDROSILYLATION OF OLEFINS

LU Xueran; CHEN Zhen; DUAN Heping; CHEN Yifan

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SYNTHESIS OF POLYSILOXANE-SUPPORTED SELENAETHER PLATINUM COMPLEX AND ITS CATALYTIC PROPERTY FOR HYDROSILYLATION OF OLEFINS

Papers | Updated：2021-06-21

- SYNTHESIS OF POLYSILOXANE-SUPPORTED SELENAETHER PLATINUM COMPLEX AND ITS CATALYTIC PROPERTY FOR HYDROSILYLATION OF OLEFINS
- SYNTHESIS OF POLYSILOXANE-SUPPORTED SELENAETHER PLATINUM COMPLEX AND ITS CATALYTIC PROPERTY FOR HYDROSILYLATION OF OLEFINS
- 高分子科学（英文版） 1996年14卷第4期页码：289-294
- Affiliations：
  
  1.   Department of Chemistry
  2.   Wuhan University
  3.   Wuhan 430072
  4.   The Center of Analysis and Measurement
  5.   Chinese Geology University
  6.   Wuhan 430074
- Author bio：
- Funds：
- DOI：
  中图分类号： TQ317
- 纸质出版：1996-12-20
- Accepted：
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[1]卢雪然,陈臻,段和平,陈亦凡.SYNTHESIS OF POLYSILOXANE-SUPPORTED SELENAETHER PLATINUM COMPLEX AND ITS CATALYTIC PROPERTY FOR HYDROSILYLATION OF OLEFINS[J].Chinese Journal of Polymer Science,1996,{4}(04):289-294.

LU Xueran, CHEN Zhen, DUAN Heping, et al. SYNTHESIS OF POLYSILOXANE-SUPPORTED SELENAETHER PLATINUM COMPLEX AND ITS CATALYTIC PROPERTY FOR HYDROSILYLATION OF OLEFINS[J]. 1996, 14(4): 289-294.
[1]卢雪然,陈臻,段和平,陈亦凡.SYNTHESIS OF POLYSILOXANE-SUPPORTED SELENAETHER PLATINUM COMPLEX AND ITS CATALYTIC PROPERTY FOR HYDROSILYLATION OF OLEFINS[J].Chinese Journal of Polymer Science,1996,{4}(04):289-294. DOI：

LU Xueran, CHEN Zhen, DUAN Heping, et al. SYNTHESIS OF POLYSILOXANE-SUPPORTED SELENAETHER PLATINUM COMPLEX AND ITS CATALYTIC PROPERTY FOR HYDROSILYLATION OF OLEFINS[J]. 1996, 14(4): 289-294. DOI：

摘要

<正> A new type of selenious polymer

silica-bound polybispropoxyethyl-selenidesilsesquioxane

and its platinum complex were synthesized from bis-allyloxyethyl selenide via hydrosily-lation with triethoxysilane

followed by immobilized on fumed silica

and then reactingwith potassium chloroplatinite under nitrogen atmosphere in acetone. It was found thatthe platinum complex can catalyze the hydrosilylation of olefins with triethoxysilane effec-tively The effects of the nature of the substrate

the amount of complex used

and thereaction temperature on the catalytic activity were investigated.

Abstract

A new type of selenious polymer

silica-bound polybispropoxyethyl-selenidesilsesquioxane

and its platinum complex were synthesized from bis-allyloxyethyl selenide via hydrosily-lation with triethoxysilane

followed by immobilized on fumed silica

the amount of complex used

and thereaction temperature on the catalytic activity were investigated.

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