NONLINEAR OPTICAL PROPERTIES OF A-SHAPED NITROPYRIMIDINE DERIVATIVES AND ITS POLYMERIC FILMS*

XIANG Yingxu; YE Cheng

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NONLINEAR OPTICAL PROPERTIES OF A-SHAPED NITROPYRIMIDINE DERIVATIVES AND ITS POLYMERIC FILMS*

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- NONLINEAR OPTICAL PROPERTIES OF A-SHAPED NITROPYRIMIDINE DERIVATIVES AND ITS POLYMERIC FILMS*
- NONLINEAR OPTICAL PROPERTIES OF A-SHAPED NITROPYRIMIDINE DERIVATIVES AND ITS POLYMERIC FILMS*
- 高分子科学（英文版） 1996年14卷第4期页码：362-367
- Affiliations：
  
  1.   Organic Solid Lab.
  2.   Institute of Chemistry
  3.   Chinese Academy of Sciences
  4.   Beijing 100080
- Author bio：
- Funds：
- DOI：
  中图分类号： TQ320.721
- 纸质出版：1996-12-20
- Accepted：
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[1]相莹许,叶成.NONLINEAR OPTICAL PROPERTIES OF A-SHAPED NITROPYRIMIDINE DERIVATIVES AND ITS POLYMERIC FILMS[J].Chinese Journal of Polymer Science,1996,{4}(04):362-367.

XIANG Yingxu, YE Cheng. NONLINEAR OPTICAL PROPERTIES OF A-SHAPED NITROPYRIMIDINE DERIVATIVES AND ITS POLYMERIC FILMS*[J]. 1996, 14(4): 362-367.
[1]相莹许,叶成.NONLINEAR OPTICAL PROPERTIES OF A-SHAPED NITROPYRIMIDINE DERIVATIVES AND ITS POLYMERIC FILMS[J].Chinese Journal of Polymer Science,1996,{4}(04):362-367. DOI：

XIANG Yingxu, YE Cheng. NONLINEAR OPTICAL PROPERTIES OF A-SHAPED NITROPYRIMIDINE DERIVATIVES AND ITS POLYMERIC FILMS*[J]. 1996, 14(4): 362-367. DOI：

摘要

正

Three A-shaped nitropyrimidine derivatives with benzyl or furfuryl as bridge havebeen synthesized. They possess shorter absorption wavelengths (λ

cut-off

)

400 nm) andhigher βμ values (around 10

-46

esu). The second order nonlinear optical coefficient d

ofpoled BNPMOPMDA/PMMA doped film is 1.2-2.0×10

-9

esu obtained by in-situ SHGmeasurements. It can be expected that the chromophore-functionalized polymer containinghigher number density of synthesized chromophore as side chain will be the potential blue-light transparent frequency doubling materials.

Abstract

Three A-shaped nitropyrimidine derivatives with benzyl or furfuryl as bridge havebeen synthesized. They possess shorter absorption wavelengths (λ

cut-off

)

400 nm) andhigher βμ values (around 10

-46

esu). The second order nonlinear optical coefficient d

ofpoled BNPMOPMDA/PMMA doped film is 1.2-2.0×10

-9

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