SYNTHESIS AND CHARACTERIZATION OF A SILICA-SUPPORTED CARBOXYMETHYLCELLULOSE PLATINUM COMPLEX AND ITS CATALYTIC BEHAVIORS FOR HYDROGENATI0N OF AR0MATICS

TANG Liming; HUANG Meiyu; JIANG Yingyan

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SYNTHESIS AND CHARACTERIZATION OF A SILICA-SUPPORTED CARBOXYMETHYLCELLULOSE PLATINUM COMPLEX AND ITS CATALYTIC BEHAVIORS FOR HYDROGENATI0N OF AR0MATICS

Papers | Updated：2021-06-21

- SYNTHESIS AND CHARACTERIZATION OF A SILICA-SUPPORTED CARBOXYMETHYLCELLULOSE PLATINUM COMPLEX AND ITS CATALYTIC BEHAVIORS FOR HYDROGENATI0N OF AR0MATICS
- SYNTHESIS AND CHARACTERIZATION OF A SILICA-SUPPORTED CARBOXYMETHYLCELLULOSE PLATINUM COMPLEX AND ITS CATALYTIC BEHAVIORS FOR HYDROGENATI0N OF AR0MATICS
- 高分子科学（英文版） 1996年14卷第3期页码：199-204
- Affiliations：
  
  1.   Institute of Chemistry
  2.   Academia Sinica
  3.   Beijing 100080
- Author bio：
- Funds：
- DOI：
  中图分类号： O643.3
- 纸质出版：1996-09-20
- Accepted：
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[1]唐黎明,黄美玉,江英彦.SYNTHESIS AND CHARACTERIZATION OF A SILICA-SUPPORTED CARBOXYMETHYLCELLULOSE PLATINUM COMPLEX AND ITS CATALYTIC BEHAVIORS FOR HYDROGENATI0N OF AR0MATICS[J].Chinese Journal of Polymer Science,1996,{4}(03):199-204.

TANG Liming, HUANG Meiyu, JIANG Yingyan. SYNTHESIS AND CHARACTERIZATION OF A SILICA-SUPPORTED CARBOXYMETHYLCELLULOSE PLATINUM COMPLEX AND ITS CATALYTIC BEHAVIORS FOR HYDROGENATI0N OF AR0MATICS[J]. 1996, 14(3): 199-204.
[1]唐黎明,黄美玉,江英彦.SYNTHESIS AND CHARACTERIZATION OF A SILICA-SUPPORTED CARBOXYMETHYLCELLULOSE PLATINUM COMPLEX AND ITS CATALYTIC BEHAVIORS FOR HYDROGENATI0N OF AR0MATICS[J].Chinese Journal of Polymer Science,1996,{4}(03):199-204. DOI：

TANG Liming, HUANG Meiyu, JIANG Yingyan. SYNTHESIS AND CHARACTERIZATION OF A SILICA-SUPPORTED CARBOXYMETHYLCELLULOSE PLATINUM COMPLEX AND ITS CATALYTIC BEHAVIORS FOR HYDROGENATI0N OF AR0MATICS[J]. 1996, 14(3): 199-204. DOI：

摘要

正

A silica-supported carboxymethylcellulose platinum complex （abbreviated as SiO

-CMC-Pt） has been prepared and characterized by XPS. Its catalytic properties for hydro-genation of aromatic compounds were studied. The results showed that this catalystcould catalyze the hydrogenation of phenol

anisol

p-cresol

benzene and toluene to cyclo-hexanol

cyclohexyl methyl ether

p-methyl cyclohexanol

cyclohexane and methylcyclo-hexane

respectively in 100% yield at 30℃ and 1 atm. In the hydrogenation of phenol

COO/Pt ratio in SiO

-CMC-Pt has much influence on the initial hydrogenation rate andthe selectivity for the intermediate product

cyclohexanone. The highest initial rate andthe highest yield of cyclohexanone both occur at COO/Pt ratio of 6. The complex is stableduring the reaction and can be used repeatedly.

Abstract

A silica-supported carboxymethylcellulose platinum complex （abbreviated as SiO

anisol

p-cresol

benzene and toluene to cyclo-hexanol

cyclohexyl methyl ether

p-methyl cyclohexanol

cyclohexane and methylcyclo-hexane

respectively in 100% yield at 30℃ and 1 atm. In the hydrogenation of phenol

COO/Pt ratio in SiO

-CMC-Pt has much influence on the initial hydrogenation rate andthe selectivity for the intermediate product

cyclohexanone. The highest initial rate andthe highest yield of cyclohexanone both occur at COO/Pt ratio of 6. The complex is stableduring the reaction and can be used repeatedly.

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