SYNTHESES OF STYRENE-METHYL METHACRYLATE BLOCK COPOLYMER BY POLYAZOAMIDE AS INITIATOR
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SYNTHESES OF STYRENE-METHYL METHACRYLATE BLOCK COPOLYMER BY POLYAZOAMIDE AS INITIATOR
SYNTHESES OF STYRENE-METHYL METHACRYLATE BLOCK COPOLYMER BY POLYAZOAMIDE AS INITIATOR
高分子科学(英文版)1996年14卷第3期 页码:211-216
Affiliations:
1. Chengdu Institute of Organic Chemistry
2. Academia Sinica
3. Chengdu Sichuan reearch Institute of Building Materials ,610015
4. Chengdu 610081
Author bio:
Funds:
DOI:
中图分类号:TQ317
纸质出版:1996-09-20
Accepted:
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[1]王忠义,魏德卿.SYNTHESES OF STYRENE-METHYL METHACRYLATE BLOCK COPOLYMER BY POLYAZOAMIDE AS INITIATOR[J].Chinese Journal of Polymer Science,1996,{4}(03):211-216.
WANG Zhongyi, WEI Deqing. SYNTHESES OF STYRENE-METHYL METHACRYLATE BLOCK COPOLYMER BY POLYAZOAMIDE AS INITIATOR[J]. 1996, 14(3): 211-216.
[1]王忠义,魏德卿.SYNTHESES OF STYRENE-METHYL METHACRYLATE BLOCK COPOLYMER BY POLYAZOAMIDE AS INITIATOR[J].Chinese Journal of Polymer Science,1996,{4}(03):211-216.DOI:
WANG Zhongyi, WEI Deqing. SYNTHESES OF STYRENE-METHYL METHACRYLATE BLOCK COPOLYMER BY POLYAZOAMIDE AS INITIATOR[J]. 1996, 14(3): 211-216.DOI:
SYNTHESES OF STYRENE-METHYL METHACRYLATE BLOCK COPOLYMER BY POLYAZOAMIDE AS INITIATOR
Polyazoamide(PAA) was used as initiator to prepare block copolymer P(MMA-b-St) byfree radical polymerization. The fraction of block copolymer was about 50%. The structureof the block-copolymer was characterized by IR and the results of
1
H-NMR and GPCshowed that the content of the block and the molecular weight (M
w
) of the prepolymerand block copolymer could be controlled by varying the mol ratio of styrene/PAA andMMA/prepolymer. DSC and TEM results revealed that the block copolymer has twoseparated glass transition temperatures and phase separation within the domain structure.
Abstract
Polyazoamide(PAA) was used as initiator to prepare block copolymer P(MMA-b-St) byfree radical polymerization. The fraction of block copolymer was about 50%. The structureof the block-copolymer was characterized by IR and the results of
1
H-NMR and GPCshowed that the content of the block and the molecular weight (M
w
) of the prepolymerand block copolymer could be controlled by varying the mol ratio of styrene/PAA andMMA/prepolymer. DSC and TEM results revealed that the block copolymer has twoseparated glass transition temperatures and phase separation within the domain structure.
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