HYDROGENATION OF PHENOL AND CRESOLS CATALYZED BY CHITOSAN SUPPORTED PALLADIUM COMPLEX AT MILD CONDITIONS

TANG Liming; HUANG Meiyu; JIANG Yingyan

Your Location：

Home >

Browse articles >

HYDROGENATION OF PHENOL AND CRESOLS CATALYZED BY CHITOSAN SUPPORTED PALLADIUM COMPLEX AT MILD CONDITIONS

Papers | Updated：2021-06-21

- HYDROGENATION OF PHENOL AND CRESOLS CATALYZED BY CHITOSAN SUPPORTED PALLADIUM COMPLEX AT MILD CONDITIONS
- HYDROGENATION OF PHENOL AND CRESOLS CATALYZED BY CHITOSAN SUPPORTED PALLADIUM COMPLEX AT MILD CONDITIONS
- 高分子科学（英文版） 1996年14卷第1期页码：57-62
- Affiliations：
  
  1.   Institute of Chemistry
  2.   Academia Sinica
  3.   Beijing 100080
- Author bio：
- Funds：
- DOI：
  中图分类号： O643.3
- 纸质出版：1996-03-20
- Accepted：
Scan QR Code
[1]唐黎明,黄美玉,江英彦.HYDROGENATION OF PHENOL AND CRESOLS CATALYZED BY CHITOSAN SUPPORTED PALLADIUM COMPLEX AT MILD CONDITIONS[J].Chinese Journal of Polymer Science,1996(01):57-62.

TANG Liming, HUANG Meiyu, JIANG Yingyan. HYDROGENATION OF PHENOL AND CRESOLS CATALYZED BY CHITOSAN SUPPORTED PALLADIUM COMPLEX AT MILD CONDITIONS[J]. 1996, 14(1): 57-62.
[1]唐黎明,黄美玉,江英彦.HYDROGENATION OF PHENOL AND CRESOLS CATALYZED BY CHITOSAN SUPPORTED PALLADIUM COMPLEX AT MILD CONDITIONS[J].Chinese Journal of Polymer Science,1996(01):57-62. DOI：

TANG Liming, HUANG Meiyu, JIANG Yingyan. HYDROGENATION OF PHENOL AND CRESOLS CATALYZED BY CHITOSAN SUPPORTED PALLADIUM COMPLEX AT MILD CONDITIONS[J]. 1996, 14(1): 57-62. DOI：

摘要

正

A natural polymer catalyst

sillca-supported chitosan palladium complex （abbr. asSiO

-CS-Pd） was found to catalyze the hydrogenation of phenol and cresols to correspond-ing cyclohexanones in high yield and 100% selectivity at 70℃ and 1.01325×10

Pa mildconditions. N/Pd molar ratio in the complex

temperature and solvents have much infiuenceon the reaction. The reactivity order of reactants was found to be: phenol

o-cresol. The catalyst is stable during the reaction and could be repeatedly used for severaltimes without much decrease in its catalytic activity.

Abstract

A natural polymer catalyst

sillca-supported chitosan palladium complex （abbr. asSiO

-CS-Pd） was found to catalyze the hydrogenation of phenol and cresols to correspond-ing cyclohexanones in high yield and 100% selectivity at 70℃ and 1.01325×10

Pa mildconditions. N/Pd molar ratio in the complex

temperature and solvents have much infiuenceon the reaction. The reactivity order of reactants was found to be: phenol

o-cresol. The catalyst is stable during the reaction and could be repeatedly used for severaltimes without much decrease in its catalytic activity.

关键词

Keywords

references

浏览量

Downloads

CSCD

文章被引用时，请邮件提醒。

Submit

工具集

关联资源

Optically Active Helical Poly(phenyl isocyanide)s Bearing Achiral Benzanilide Pendants: from Controlled Synthesis to Enantioseparation Application

End-to-End Neuron-inspired Signal Transduction Using Organic Electrochemical Transistors

Experimental Investigation of Graphene and TiO2 Reinforced Poly(vinyl alcohol)-based Fiber Metal Laminates

One-handed Helical Poly(m-terphenyl acetylene)s with Broad Optical Activity Range from Ultraviolet-Visible to Near-infrared Regions

Manipulating Hierarchical Aggregation Structure via Film-forming Kinetics Enables Organic Photovoltaics over 20% Efficiency