SYNTHESIS AND CHARACTERIZATION OF THERMOTROPIC COPOLYESTERS AND COPOLY (ESTER-AMIDE)S CONTAINING OXYETHYLENE-ETHER AS THE SPACER*
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SYNTHESIS AND CHARACTERIZATION OF THERMOTROPIC COPOLYESTERS AND COPOLY (ESTER-AMIDE)S CONTAINING OXYETHYLENE-ETHER AS THE SPACER*
SYNTHESIS AND CHARACTERIZATION OF THERMOTROPIC COPOLYESTERS AND COPOLY (ESTER-AMIDE)S CONTAINING OXYETHYLENE-ETHER AS THE SPACER*
高分子科学(英文版)1995年13卷第4期 页码:353-360
Affiliations:
1. Polymer Physics Laboratory
2. Changchun Institute of Applied Chemistry
3. Academia Sinica
4. Changchun 130022
Author bio:
Funds:
DOI:
中图分类号:O631
纸质出版:1995-12-20
Accepted:
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[1]王尚尔,莫志深,张宏放,冯之榴.SYNTHESIS AND CHARACTERIZATION OF THERMOTROPIC COPOLYESTERS AND COPOLY (ESTER-AMIDE)S CONTAINING OXYETHYLENE-ETHER AS THE SPACER[J].Chinese Journal of Polymer Science,1995,{4}(04):353-360.
WANG Shanger, MO Zhishen, ZHANG Hongfang, et al. SYNTHESIS AND CHARACTERIZATION OF THERMOTROPIC COPOLYESTERS AND COPOLY (ESTER-AMIDE)S CONTAINING OXYETHYLENE-ETHER AS THE SPACER*[J]. 1995, 13(4): 353-360.
[1]王尚尔,莫志深,张宏放,冯之榴.SYNTHESIS AND CHARACTERIZATION OF THERMOTROPIC COPOLYESTERS AND COPOLY (ESTER-AMIDE)S CONTAINING OXYETHYLENE-ETHER AS THE SPACER[J].Chinese Journal of Polymer Science,1995,{4}(04):353-360.DOI:
WANG Shanger, MO Zhishen, ZHANG Hongfang, et al. SYNTHESIS AND CHARACTERIZATION OF THERMOTROPIC COPOLYESTERS AND COPOLY (ESTER-AMIDE)S CONTAINING OXYETHYLENE-ETHER AS THE SPACER*[J]. 1995, 13(4): 353-360.DOI:
SYNTHESIS AND CHARACTERIZATION OF THERMOTROPIC COPOLYESTERS AND COPOLY (ESTER-AMIDE)S CONTAINING OXYETHYLENE-ETHER AS THE SPACER*
<正> Flexible oxyethylene-ether was introduced into the aromatic copolyesters and copoly(es-ter-amide)s to reduce the melting point of resulting polymers. The melting point was greatlyreduced to 200℃ or even lower in some cases
and the molecular weight was satisfactorilyhigh as reflected by inherent viscosity. The polymers exhibited high thermal stability and goodmechanical properties as determined by TGA and mechanical tests. The copolyester showedbetter crystallinity and liquid crystallinity than corresponding copoly(ester-amide)s with simi-lar monomer composition as reflected by POM observation and WAXD study. The meltingpoints for both copolyesters and copoly (ester-amide)s showed great dependence on the p-acetoxybenzoic acid (PAB) content in monomer composition and reached the lowest valuewhen PAB was 29 mol%.
Abstract
Flexible oxyethylene-ether was introduced into the aromatic copolyesters and copoly(es-ter-amide)s to reduce the melting point of resulting polymers. The melting point was greatlyreduced to 200℃ or even lower in some cases
and the molecular weight was satisfactorilyhigh as reflected by inherent viscosity. The polymers exhibited high thermal stability and goodmechanical properties as determined by TGA and mechanical tests. The copolyester showedbetter crystallinity and liquid crystallinity than corresponding copoly(ester-amide)s with simi-lar monomer composition as reflected by POM observation and WAXD study. The meltingpoints for both copolyesters and copoly (ester-amide)s showed great dependence on the p-acetoxybenzoic acid (PAB) content in monomer composition and reached the lowest valuewhen PAB was 29 mol%.
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