STUDY ON HIGHLY ACTIVE ZIEGLERNATTA CATALYSTS FOR POLYMERIZATION OF OLEFINS*
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STUDY ON HIGHLY ACTIVE ZIEGLERNATTA CATALYSTS FOR POLYMERIZATION OF OLEFINS*
STUDY ON HIGHLY ACTIVE ZIEGLERNATTA CATALYSTS FOR POLYMERIZATION OF OLEFINS*
高分子科学(英文版)1995年13卷第1期 页码:41-50
Affiliations:
1. Department of Polymer Science and Engineering
2. Zhejiang University
3. Hangzhou 310027
Author bio:
Funds:
DOI:
中图分类号:TQ317
纸质出版:1995-03-20
Accepted:
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[1]王立,封麟先,徐君庭,杨士林.STUDY ON HIGHLY ACTIVE ZIEGLERNATTA CATALYSTS FOR POLYMERIZATION OF OLEFINS[J].Chinese Journal of Polymer Science,1995,{4}(01):41-50.
WANG Li, Feng Linxian, XU Junting, et al. STUDY ON HIGHLY ACTIVE ZIEGLERNATTA CATALYSTS FOR POLYMERIZATION OF OLEFINS*[J]. 1995, 13(1): 41-50.
[1]王立,封麟先,徐君庭,杨士林.STUDY ON HIGHLY ACTIVE ZIEGLERNATTA CATALYSTS FOR POLYMERIZATION OF OLEFINS[J].Chinese Journal of Polymer Science,1995,{4}(01):41-50.DOI:
WANG Li, Feng Linxian, XU Junting, et al. STUDY ON HIGHLY ACTIVE ZIEGLERNATTA CATALYSTS FOR POLYMERIZATION OF OLEFINS*[J]. 1995, 13(1): 41-50.DOI:
STUDY ON HIGHLY ACTIVE ZIEGLERNATTA CATALYSTS FOR POLYMERIZATION OF OLEFINS*
using di-n-butyl phthalate (DNBP) as internal donor and diphenyl dimethoxyl silane(DPDMS) as external donor
have been prepared. The conditions controlling the treatment ofsupport were studied. The interactions of various components present in the catalysts and theirinfluences on catalytic performance were investigated. It is found that by using DNBP and DPDMSas internal and external donors together the polymer products with higher isotactic index can beobtained. Plausible structure model and mechanism were proposed.
Abstract
In this paper
highly active Ziegler-Natta catalysts of MgCl
2
supported TiCl
4
for synthesis ofpolyolefins
using di-n-butyl phthalate (DNBP) as internal donor and diphenyl dimethoxyl silane(DPDMS) as external donor
have been prepared. The conditions controlling the treatment ofsupport were studied. The interactions of various components present in the catalysts and theirinfluences on catalytic performance were investigated. It is found that by using DNBP and DPDMSas internal and external donors together the polymer products with higher isotactic index can beobtained. Plausible structure model and mechanism were proposed.
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