SYNTHESIS OF POLYBUTADIENE MACROINITIATOR AND POLYBUTADIENE/POLYACRYLAMIDE BLOCK COPOLYMERS*

FANG Tianru; WANG Jiahang; FANG Zheng; LIU Peiyan

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SYNTHESIS OF POLYBUTADIENE MACROINITIATOR AND POLYBUTADIENE/POLYACRYLAMIDE BLOCK COPOLYMERS*

Papers | Updated：2021-06-21

- SYNTHESIS OF POLYBUTADIENE MACROINITIATOR AND POLYBUTADIENE/POLYACRYLAMIDE BLOCK COPOLYMERS*
- SYNTHESIS OF POLYBUTADIENE MACROINITIATOR AND POLYBUTADIENE/POLYACRYLAMIDE BLOCK COPOLYMERS*
- 高分子科学（英文版） 1995年13卷第3期页码：244-251
- Affiliations：
  
  1.   Changchun Institute of Applied Chemistry
  2.   Academia Sinica
  3.   Changchun 130022
  4.   Department of Chemistry
  5.   The Northeast Normal University
  6.   Changchun 130024
- Author bio：
- Funds：
- DOI：
  中图分类号： TQ317
- 纸质出版：1995-09-20
- Accepted：
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[1]方天如,王家行,方政,刘沛妍.SYNTHESIS OF POLYBUTADIENE MACROINITIATOR AND POLYBUTADIENE/POLYACRYLAMIDE BLOCK COPOLYMERS[J].Chinese Journal of Polymer Science,1995,{4}(03):244-251.

FANG Tianru, WANG Jiahang, FANG Zheng, et al. SYNTHESIS OF POLYBUTADIENE MACROINITIATOR AND POLYBUTADIENE/POLYACRYLAMIDE BLOCK COPOLYMERS*[J]. 1995, 13(3): 244-251.
[1]方天如,王家行,方政,刘沛妍.SYNTHESIS OF POLYBUTADIENE MACROINITIATOR AND POLYBUTADIENE/POLYACRYLAMIDE BLOCK COPOLYMERS[J].Chinese Journal of Polymer Science,1995,{4}(03):244-251. DOI：

FANG Tianru, WANG Jiahang, FANG Zheng, et al. SYNTHESIS OF POLYBUTADIENE MACROINITIATOR AND POLYBUTADIENE/POLYACRYLAMIDE BLOCK COPOLYMERS*[J]. 1995, 13(3): 244-251. DOI：

摘要

<正> An azo-group containing polybutadiene macroinitiator was prepared by Pinner synthesisand characterized by IR

NMR

GPC

viscosity and elemental measurements. Themacroinitiator was further used to polymerize acrylamide （AAm） in benzene to formpolybutadiene/polyacrylamide （PBD/PAAm） block copolymers. High conversion of AAm wasobtained over a wide range of monomer/macroinitiator ratios. The PBD/PAAm blockcopolymers.were found to have excellent solvent resistance.

Abstract

An azo-group containing polybutadiene macroinitiator was prepared by Pinner synthesisand characterized by IR

NMR

GPC

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