SYNTHESES AND CHARACTERIZATION OF A NEW TYPE OF LIQUID CRYSTALLINE POLYESTERS*
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SYNTHESES AND CHARACTERIZATION OF A NEW TYPE OF LIQUID CRYSTALLINE POLYESTERS*
SYNTHESES AND CHARACTERIZATION OF A NEW TYPE OF LIQUID CRYSTALLINE POLYESTERS*
高分子科学(英文版)1994年12卷第3期 页码:221-227
Affiliations:
1. Department of Materials Science and Engineering
2. University of Science and Technology of China
3. Hefei
4. Anhui
5. 230026
6. Institute of Industrial Science
7. Faculty of Engineering
8. University of Tokyo
9. Roppongi
10. Minato-ku
11. Tokyo 106
12. Japan
Author bio:
Funds:
DOI:
中图分类号:O632
纸质出版:1994-09-20
Accepted:
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[1]白如科,吴承佩,邹应芳,孙武,潘才元,Toshiyuki Uryu.SYNTHESES AND CHARACTERIZATION OF A NEW TYPE OF LIQUID CRYSTALLINE POLYESTERS[J].Chinese Journal of Polymer Science,1994,{4}(03):221-227.
BAI Ruke, WU Chengpei, ZOU Yingfeng, et al. SYNTHESES AND CHARACTERIZATION OF A NEW TYPE OF LIQUID CRYSTALLINE POLYESTERS*[J]. 1994, 12(3): 221-227.
[1]白如科,吴承佩,邹应芳,孙武,潘才元,Toshiyuki Uryu.SYNTHESES AND CHARACTERIZATION OF A NEW TYPE OF LIQUID CRYSTALLINE POLYESTERS[J].Chinese Journal of Polymer Science,1994,{4}(03):221-227.DOI:
BAI Ruke, WU Chengpei, ZOU Yingfeng, et al. SYNTHESES AND CHARACTERIZATION OF A NEW TYPE OF LIQUID CRYSTALLINE POLYESTERS*[J]. 1994, 12(3): 221-227.DOI:
SYNTHESES AND CHARACTERIZATION OF A NEW TYPE OF LIQUID CRYSTALLINE POLYESTERS*
<正> A new type of liquid crystalline polyesters with resorcin as one part of the mesogenic unitconnected together by polymethylene
or phenylene group
and lateral groups consisting of arigid azobenzene as another part of the mesogenic unit were synthesized by interfacialpolymerization of diacyl chlorides in 1
2-dichloroethane and 2
4-dihydroxy-4’-nitroazobenzen inaqueous alkaline solution. The polyester structures were confirmed by proton NMR and IRspectra. Their phase transition behavior and texture were studied by polarizing microscopy andDSC.
Abstract
A new type of liquid crystalline polyesters with resorcin as one part of the mesogenic unitconnected together by polymethylene
or phenylene group
and lateral groups consisting of arigid azobenzene as another part of the mesogenic unit were synthesized by interfacialpolymerization of diacyl chlorides in 1
2-dichloroethane and 2
4-dihydroxy-4’-nitroazobenzen inaqueous alkaline solution. The polyester structures were confirmed by proton NMR and IRspectra. Their phase transition behavior and texture were studied by polarizing microscopy andDSC.
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