NETWORK CROWN ETHER POLYMERS WITH CENTRIC FUNCTIONAL GROUP (Ⅳ) SYNTHESIS OF NETWORK CROWN ETHER POLYMER WITH PENDANT DIETHYLAMINO THIAALKYL GROUP AND ITS PLATINUM COMPLEX*

CHEN Yuanyin; MENG Lingzhi; YIN Yihua; GENG Chengai

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NETWORK CROWN ETHER POLYMERS WITH CENTRIC FUNCTIONAL GROUP (Ⅳ) SYNTHESIS OF NETWORK CROWN ETHER POLYMER WITH PENDANT DIETHYLAMINO THIAALKYL GROUP AND ITS PLATINUM COMPLEX*

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- NETWORK CROWN ETHER POLYMERS WITH CENTRIC FUNCTIONAL GROUP (Ⅳ) SYNTHESIS OF NETWORK CROWN ETHER POLYMER WITH PENDANT DIETHYLAMINO THIAALKYL GROUP AND ITS PLATINUM COMPLEX*
- NETWORK CROWN ETHER POLYMERS WITH CENTRIC FUNCTIONAL GROUP (Ⅳ) SYNTHESIS OF NETWORK CROWN ETHER POLYMER WITH PENDANT DIETHYLAMINO THIAALKYL GROUP AND ITS PLATINUM COMPLEX*
- 高分子科学（英文版） 1994年12卷第4期页码：316-322
- Affiliations：
  
  1.   Department of Chemistry
  2.   Wuhan University
  3.   Wuhan 430072
  4.   The Second Middle School in Caidian
  5.   Wuhan 430100
- Author bio：
- Funds：
- DOI：
  中图分类号： O631
- 纸质出版：1994-12-20
- Accepted：
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[1]陈远荫,孟令芝,殷以华,耿成爱.NETWORK CROWN ETHER POLYMERS WITH CENTRIC FUNCTIONAL GROUP (Ⅳ) SYNTHESIS OF NETWORK CROWN ETHER POLYMER WITH PENDANT DIETHYLAMINO THIAALKYL GROUP AND ITS PLATINUM COMPLEX[J].Chinese Journal of Polymer Science,1994,{4}(04):316-322.

CHEN Yuanyin, MENG Lingzhi, YIN Yihua, et al. NETWORK CROWN ETHER POLYMERS WITH CENTRIC FUNCTIONAL GROUP (Ⅳ) SYNTHESIS OF NETWORK CROWN ETHER POLYMER WITH PENDANT DIETHYLAMINO THIAALKYL GROUP AND ITS PLATINUM COMPLEX*[J]. 1994, 12(4): 316-322.
[1]陈远荫,孟令芝,殷以华,耿成爱.NETWORK CROWN ETHER POLYMERS WITH CENTRIC FUNCTIONAL GROUP (Ⅳ) SYNTHESIS OF NETWORK CROWN ETHER POLYMER WITH PENDANT DIETHYLAMINO THIAALKYL GROUP AND ITS PLATINUM COMPLEX[J].Chinese Journal of Polymer Science,1994,{4}(04):316-322. DOI：

CHEN Yuanyin, MENG Lingzhi, YIN Yihua, et al. NETWORK CROWN ETHER POLYMERS WITH CENTRIC FUNCTIONAL GROUP (Ⅳ) SYNTHESIS OF NETWORK CROWN ETHER POLYMER WITH PENDANT DIETHYLAMINO THIAALKYL GROUP AND ITS PLATINUM COMPLEX*[J]. 1994, 12(4): 316-322. DOI：

摘要

<正> The title polymer was prepared from 5-diethylamino-3-thia-pentyl glycidyl ether anddiethylene glycol bisglycidyl ether via ring-opening copolymerization. It was found that thisreaction could be catalyzed by sodium

but not Lewis acid. The obtained polymer can coordinatewith platinum compound

and the platinum complex is a new kind of catalyst for thehydrosilylation of olefins with triethoxysilane.

Abstract

The title polymer was prepared from 5-diethylamino-3-thia-pentyl glycidyl ether anddiethylene glycol bisglycidyl ether via ring-opening copolymerization. It was found that thisreaction could be catalyzed by sodium

but not Lewis acid. The obtained polymer can coordinatewith platinum compound

and the platinum complex is a new kind of catalyst for thehydrosilylation of olefins with triethoxysilane.

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