THE NON—ISOTHERMAL CRYSTALLIZATION KINETICS OF A LIQUID CRYSTALLINE RANDOM COPOLYESTER WITH DIFFERENT COMPOSITIONS
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THE NON—ISOTHERMAL CRYSTALLIZATION KINETICS OF A LIQUID CRYSTALLINE RANDOM COPOLYESTER WITH DIFFERENT COMPOSITIONS
THE NON—ISOTHERMAL CRYSTALLIZATION KINETICS OF A LIQUID CRYSTALLINE RANDOM COPOLYESTER WITH DIFFERENT COMPOSITIONS
高分子科学(英文版)1994年12卷第1期 页码:44-48
Affiliations:
1. Department of Chemistry
2. University of Xiangtan
3. Hunan 411105
Author bio:
Funds:
DOI:
中图分类号:O631.5
纸质出版:1994-03-20
Accepted:
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[1]董炎明,李志敏.THE NON—ISOTHERMAL CRYSTALLIZATION KINETICS OF A LIQUID CRYSTALLINE RANDOM COPOLYESTER WITH DIFFERENT COMPOSITIONS[J].Chinese Journal of Polymer Science,1994,{4}(01):44-48.
DONG Yanming, LI Zhimin. THE NON—ISOTHERMAL CRYSTALLIZATION KINETICS OF A LIQUID CRYSTALLINE RANDOM COPOLYESTER WITH DIFFERENT COMPOSITIONS[J]. 1994, 12(1): 44-48.
[1]董炎明,李志敏.THE NON—ISOTHERMAL CRYSTALLIZATION KINETICS OF A LIQUID CRYSTALLINE RANDOM COPOLYESTER WITH DIFFERENT COMPOSITIONS[J].Chinese Journal of Polymer Science,1994,{4}(01):44-48.DOI:
DONG Yanming, LI Zhimin. THE NON—ISOTHERMAL CRYSTALLIZATION KINETICS OF A LIQUID CRYSTALLINE RANDOM COPOLYESTER WITH DIFFERENT COMPOSITIONS[J]. 1994, 12(1): 44-48.DOI:
THE NON—ISOTHERMAL CRYSTALLIZATION KINETICS OF A LIQUID CRYSTALLINE RANDOM COPOLYESTER WITH DIFFERENT COMPOSITIONS
<正> The non-isothermal crystallization kinetics analysis of liquid crystalline random copolyestercomposed of p-oxybenzoate (B) and 2
6-oxynaphthoate (N) monomers was carried out by meansof differential scanning calorimetry basing on Ziabicki and Jeziorny method. Although the compo-sition of 58/42 B-N copolyester had poorer thermodynamic crystallizability comparing with thoseof 30/70 and 75/25
its kinetic crystallizability Go was slightly larger. This fact was due to thepoorer match of sequences of 58/42 B-N in domains of nematic melt
and therefore better mobilityof chains during crystallization. The Avrami exponents of three composition species were allabout 2. 5
implying two dimensional growth in so-called non-periodic layer crystallites and a mixture of homogeneous and heterogeneous nucleation.
Abstract
The non-isothermal crystallization kinetics analysis of liquid crystalline random copolyestercomposed of p-oxybenzoate (B) and 2
6-oxynaphthoate (N) monomers was carried out by meansof differential scanning calorimetry basing on Ziabicki and Jeziorny method. Although the compo-sition of 58/42 B-N copolyester had poorer thermodynamic crystallizability comparing with thoseof 30/70 and 75/25
its kinetic crystallizability Go was slightly larger. This fact was due to thepoorer match of sequences of 58/42 B-N in domains of nematic melt
and therefore better mobilityof chains during crystallization. The Avrami exponents of three composition species were allabout 2. 5
implying two dimensional growth in so-called non-periodic layer crystallites and a mixture of homogeneous and heterogeneous nucleation.
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