THE EFFECT OF MONOMERS FEEDING METHODS ON EMULSION COPOLYMERIZATION OF VINYLIDENE CHLORIDE AND ACRYLATES*
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THE EFFECT OF MONOMERS FEEDING METHODS ON EMULSION COPOLYMERIZATION OF VINYLIDENE CHLORIDE AND ACRYLATES*
THE EFFECT OF MONOMERS FEEDING METHODS ON EMULSION COPOLYMERIZATION OF VINYLIDENE CHLORIDE AND ACRYLATES*
高分子科学(英文版)1994年12卷第1期 页码:66-72
Affiliations:
1. Dapartment of Applied Chemistry
2. Beijing Institute of Chemical Technology
3. Beijing 100013
Author bio:
Funds:
DOI:
中图分类号:TQ316.334
纸质出版:1994-03-20
Accepted:
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[1]余鼎声,唐少华,焦书科.THE EFFECT OF MONOMERS FEEDING METHODS ON EMULSION COPOLYMERIZATION OF VINYLIDENE CHLORIDE AND ACRYLATES[J].Chinese Journal of Polymer Science,1994,{4}(01):66-72.
YU Dingsheng, TANG Shaohua, JIAO Shuke. THE EFFECT OF MONOMERS FEEDING METHODS ON EMULSION COPOLYMERIZATION OF VINYLIDENE CHLORIDE AND ACRYLATES*[J]. 1994, 12(1): 66-72.
[1]余鼎声,唐少华,焦书科.THE EFFECT OF MONOMERS FEEDING METHODS ON EMULSION COPOLYMERIZATION OF VINYLIDENE CHLORIDE AND ACRYLATES[J].Chinese Journal of Polymer Science,1994,{4}(01):66-72.DOI:
YU Dingsheng, TANG Shaohua, JIAO Shuke. THE EFFECT OF MONOMERS FEEDING METHODS ON EMULSION COPOLYMERIZATION OF VINYLIDENE CHLORIDE AND ACRYLATES*[J]. 1994, 12(1): 66-72.DOI:
THE EFFECT OF MONOMERS FEEDING METHODS ON EMULSION COPOLYMERIZATION OF VINYLIDENE CHLORIDE AND ACRYLATES*
<正> The emulsion copolymerization of vinylidene chloride (VDC) with methyl-methacrylate(MMA) and acrylonitrile (AN) was carried out by batch
seeded batch and semicontinuous pro-cesses
respectively. Significant differences were found in the physical and mechanical propertiesof the latexes and films
depending on the methods of monomer feeding. The results both intheory and experiments demonstrated that the copolymer composition and the length of the VDC sequences in the copolymer could be controlled by the modes of monomer feeding process.
Abstract
The emulsion copolymerization of vinylidene chloride (VDC) with methyl-methacrylate(MMA) and acrylonitrile (AN) was carried out by batch
seeded batch and semicontinuous pro-cesses
respectively. Significant differences were found in the physical and mechanical propertiesof the latexes and films
depending on the methods of monomer feeding. The results both intheory and experiments demonstrated that the copolymer composition and the length of the VDC sequences in the copolymer could be controlled by the modes of monomer feeding process.
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