A NEW METHOD ON THE CHEMICAL SYNTHESIS OF DOPED POLYPYRROLE INITIATED BY CuCl2-C2H5OH SYSTEM
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A NEW METHOD ON THE CHEMICAL SYNTHESIS OF DOPED POLYPYRROLE INITIATED BY CuCl2-C2H5OH SYSTEM
A NEW METHOD ON THE CHEMICAL SYNTHESIS OF DOPED POLYPYRROLE INITIATED BY CuCl2-C2H5OH SYSTEM
高分子科学(英文版)1993年11卷第4期 页码:337-341
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纸质出版:1993-12-20
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ZHANG Jie, 佘永柏, 陆斌, 等. A NEW METHOD ON THE CHEMICAL SYNTHESIS OF DOPED POLYPYRROLE INITIATED BY CuCl2-C2H5OH SYSTEM[J]. 高分子科学(英文版), 1993,11(4):337-341.
ZHANG Jie, SHE Yongbo, LU Bin, et al. A NEW METHOD ON THE CHEMICAL SYNTHESIS OF DOPED POLYPYRROLE INITIATED BY CuCl2-C2H5OH SYSTEM[J]. 1993, 11(4): 337-341.
ZHANG Jie, 佘永柏, 陆斌, 等. A NEW METHOD ON THE CHEMICAL SYNTHESIS OF DOPED POLYPYRROLE INITIATED BY CuCl2-C2H5OH SYSTEM[J]. 高分子科学(英文版), 1993,11(4):337-341.DOI:
ZHANG Jie, SHE Yongbo, LU Bin, et al. A NEW METHOD ON THE CHEMICAL SYNTHESIS OF DOPED POLYPYRROLE INITIATED BY CuCl2-C2H5OH SYSTEM[J]. 1993, 11(4): 337-341.DOI:
A NEW METHOD ON THE CHEMICAL SYNTHESIS OF DOPED POLYPYRROLE INITIATED BY CuCl2-C2H5OH SYSTEM
Our objectives were to develop a new chemical method for the polymerization of pyrrole. CuCl2 dissolved in C2H5OH solvent is primarily used for the initiation polymerization of pyrrole. The polymers with different yield and conductivity were obtained by raring the initial concentration of Cu2+. The initial concentrations of Cu2+ varied from 1.2 × 10-4 mole to 6.48 × 10-3 mole Cu2+ with 2.16 × 10-2 mole pyrrole. The polypyrrole obtained was characterized with elemental analyzer
XPS
IR spectroscopy
Four-point probe and SEM.
Abstract
Our objectives were to develop a new chemical method for the polymerization of pyrrole. CuCl2 dissolved in C2H5OH solvent is primarily used for the initiation polymerization of pyrrole. The polymers with different yield and conductivity were obtained by raring the initial concentration of Cu2+. The initial concentrations of Cu2+ varied from 1.2 × 10-4 mole to 6.48 × 10-3 mole Cu2+ with 2.16 × 10-2 mole pyrrole. The polypyrrole obtained was characterized with elemental analyzer
XPS
IR spectroscopy
Four-point probe and SEM.
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