SYNTHESIS OF POLYSTYRENE-BLOCK-POLYCAPROLACTAM WITH 1,1-BIS-(1′-NAPHTHYL) ETHYLENE AS A DEACTIVATING AGENT
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SYNTHESIS OF POLYSTYRENE-BLOCK-POLYCAPROLACTAM WITH 1,1-BIS-(1′-NAPHTHYL) ETHYLENE AS A DEACTIVATING AGENT
SYNTHESIS OF POLYSTYRENE-BLOCK-POLYCAPROLACTAM WITH 1,1-BIS-(1′-NAPHTHYL) ETHYLENE AS A DEACTIVATING AGENT
高分子科学(英文版)1993年11卷第4期 页码:342-347
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纸质出版:1993-12-20
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JIANG Rishan, QUIRK. SYNTHESIS OF POLYSTYRENE-BLOCK-POLYCAPROLACTAM WITH 1,1-BIS-(1′-NAPHTHYL) ETHYLENE AS A DEACTIVATING AGENT[J]. 高分子科学(英文版), 1993,11(4):342-347.
JIANG Rishan, QUIRK. SYNTHESIS OF POLYSTYRENE-BLOCK-POLYCAPROLACTAM WITH 1,1-BIS-(1′-NAPHTHYL) ETHYLENE AS A DEACTIVATING AGENT[J]. 1993, 11(4): 342-347.
JIANG Rishan, QUIRK. SYNTHESIS OF POLYSTYRENE-BLOCK-POLYCAPROLACTAM WITH 1,1-BIS-(1′-NAPHTHYL) ETHYLENE AS A DEACTIVATING AGENT[J]. 高分子科学(英文版), 1993,11(4):342-347.DOI:
JIANG Rishan, QUIRK. SYNTHESIS OF POLYSTYRENE-BLOCK-POLYCAPROLACTAM WITH 1,1-BIS-(1′-NAPHTHYL) ETHYLENE AS A DEACTIVATING AGENT[J]. 1993, 11(4): 342-347.DOI:
SYNTHESIS OF POLYSTYRENE-BLOCK-POLYCAPROLACTAM WITH 1,1-BIS-(1′-NAPHTHYL) ETHYLENE AS A DEACTIVATING AGENT
1-bis (1′-naphthyl) ethylene monomer unit into the active polystyrene chain end greatly decreased the reactivity of the active chain end to the carbonyl group
and allowed the polymeric chain end to react only with the double bond in N-methacryloyl caprolactam
resulting in N-acylcaprolactam functionalized polystyrene in 100% conversion. New diblock copolymer of polystyrene with polycaprolactam was synthesized by direct reaction of the functionalized polymer with caprolactam without adding additional alkali metal or their caprolactam salts.
Abstract
The insertion of 1
1-bis (1′-naphthyl) ethylene monomer unit into the active polystyrene chain end greatly decreased the reactivity of the active chain end to the carbonyl group
and allowed the polymeric chain end to react only with the double bond in N-methacryloyl caprolactam
resulting in N-acylcaprolactam functionalized polystyrene in 100% conversion. New diblock copolymer of polystyrene with polycaprolactam was synthesized by direct reaction of the functionalized polymer with caprolactam without adding additional alkali metal or their caprolactam salts.
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