A SENSITIZED PHOTOINITIATION SYSTEM ——BIS (7-DIETHYLAMINO COUMARIN ) KETONE-3 AND DIPHENYLIODONIUM SALT COMBINATION

LI Jun; WANG Xiuzhi; YANG Yongyung; LI Miaozhen; WANG Erjian

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A SENSITIZED PHOTOINITIATION SYSTEM ——BIS (7-DIETHYLAMINO COUMARIN ) KETONE-3 AND DIPHENYLIODONIUM SALT COMBINATION

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- A SENSITIZED PHOTOINITIATION SYSTEM ——BIS (7-DIETHYLAMINO COUMARIN ) KETONE-3 AND DIPHENYLIODONIUM SALT COMBINATION
- A SENSITIZED PHOTOINITIATION SYSTEM ——BIS (7-DIETHYLAMINO COUMARIN ) KETONE-3 AND DIPHENYLIODONIUM SALT COMBINATION
- 高分子科学（英文版） 1993年11卷第3期页码：249-254
- Affiliations：
  
  1. Institute of Photographic Chemistry, Academia Sinica,Beijing
  2. Academia Sinica
  3. Beijing
- Author bio：
- Funds：
- DOI：
  中图分类号：
- 纸质出版：1993-09-20
- Accepted：
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[1]李军,汪秀智,杨永源,李妙贞,王尔.A SENSITIZED PHOTOINITIATION SYSTEM ——BIS (7-DIETHYLAMINO COUMARIN ) KETONE-3 AND DIPHENYLIODONIUM SALT COMBINATION[J].Chinese Journal of Polymer Science,1993,{4}(03):249-254.

LI Jun, WANG Xiuzhi, YANG Yongyung, et al. A SENSITIZED PHOTOINITIATION SYSTEM ——BIS (7-DIETHYLAMINO COUMARIN ) KETONE-3 AND DIPHENYLIODONIUM SALT COMBINATION[J]. 1993, 11(3): 249-254.
[1]李军,汪秀智,杨永源,李妙贞,王尔.A SENSITIZED PHOTOINITIATION SYSTEM ——BIS (7-DIETHYLAMINO COUMARIN ) KETONE-3 AND DIPHENYLIODONIUM SALT COMBINATION[J].Chinese Journal of Polymer Science,1993,{4}(03):249-254. DOI：

LI Jun, WANG Xiuzhi, YANG Yongyung, et al. A SENSITIZED PHOTOINITIATION SYSTEM ——BIS (7-DIETHYLAMINO COUMARIN ) KETONE-3 AND DIPHENYLIODONIUM SALT COMBINATION[J]. 1993, 11(3): 249-254. DOI：

摘要

正

Bis （7-diethylaminocoumarin） ketone- 3（DACK） and diphenyliodonium salt （DPIO）combination as an effective photoinitiation system for radical polymerization has been investigated. The sensitized photolysis of DACK/DPIO leads to bleaching of DACK and decomposition of DPIO to generate initiating radical species. The electron transfer sensitization occurs mainly from the triplet state of DACK. The photobleaching obeyed a second-order kinetics and the rate constant was evaluated to be 31.3mol

-1

·1·s

-1

Photopolymerization of MMA initiated by DACK/DPIO was carried out in acetonitrile solution. The polymerization rate was found to be proportional to the concentration of DACK

DPIO and MMA with the exponents of 0.34

0.40 and 1.0 respectively. The initiated efficiency is comparable to those of small molecular ketones.The sensitized photoinitiation mechanism has been discussed.

Abstract

Bis （7- diethylaminocoumarin） ketone- 3（DACK） and diphenyliodonium salt （DPIO）combination as an effective photoinitiation system for radical polymerization has been investigated. The sensitized photolysis of DACK/DPIO leads to bleaching of DACK and decomposition of DPIO to generate initiating radical species. The electron transfer sensitization occurs mainly from the triplet state of DACK. The photobleaching obeyed a second-order kinetics and the rate constant was evaluated to be 31.3mol

-1

·1·s

-1

Photopolymerization of MMA initiated by DACK/DPIO was carried out in acetonitrile solution. The polymerization rate was found to be proportional to the concentration of DACK

DPIO and MMA with the exponents of 0.34

0.40 and 1.0 respectively. The initiated efficiency is comparable to those of small molecular ketones.The sensitized photoinitiation mechanism has been discussed.

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