IONIC CONDUCTIVITY IN THE COMPLEXES OF COMB-SHAPED POLYETHER WITH LITHIUM AROMATIC SULFONATE
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IONIC CONDUCTIVITY IN THE COMPLEXES OF COMB-SHAPED POLYETHER WITH LITHIUM AROMATIC SULFONATE
IONIC CONDUCTIVITY IN THE COMPLEXES OF COMB-SHAPED POLYETHER WITH LITHIUM AROMATIC SULFONATE
高分子科学(英文版)1993年11卷第3期 页码:267-272
Affiliations:
1. Laboratory of Solid State Ionics, University of Science and Technology Beijing,Beijing,100083
2. University of Science and Technology Beijing
3. Beijing 100083
Author bio:
Funds:
DOI:
中图分类号:
纸质出版:1993-09-20
Accepted:
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[1]张升水,仇卫华,薛大翠,刘庆国.IONIC CONDUCTIVITY IN THE COMPLEXES OF COMB-SHAPED POLYETHER WITH LITHIUM AROMATIC SULFONATE[J].Chinese Journal of Polymer Science,1993,{4}(03):267-272.
ZHANG Shengshui, QIU Weihua, XUE Dacui, et al. IONIC CONDUCTIVITY IN THE COMPLEXES OF COMB-SHAPED POLYETHER WITH LITHIUM AROMATIC SULFONATE[J]. 1993, 11(3): 267-272.
[1]张升水,仇卫华,薛大翠,刘庆国.IONIC CONDUCTIVITY IN THE COMPLEXES OF COMB-SHAPED POLYETHER WITH LITHIUM AROMATIC SULFONATE[J].Chinese Journal of Polymer Science,1993,{4}(03):267-272.DOI:
ZHANG Shengshui, QIU Weihua, XUE Dacui, et al. IONIC CONDUCTIVITY IN THE COMPLEXES OF COMB-SHAPED POLYETHER WITH LITHIUM AROMATIC SULFONATE[J]. 1993, 11(3): 267-272.DOI:
IONIC CONDUCTIVITY IN THE COMPLEXES OF COMB-SHAPED POLYETHER WITH LITHIUM AROMATIC SULFONATE
Complexes of comb-shaped polyether and lithium aromatic sulfonates bearing different negative charge number were prepared by in situ thermal polymerization. Their conductivity depends deeply on salt content
ambient temperature and negative charge number of the added salts. Results show that anions can be partly immobilized by increasing their negative charges at lower temperature. Against discharge time the short circuit current of the battery (Li/complex film/Li
x
V
3
O
8
) is stabilized by increasing the anionic charge number of the complex.
Abstract
Complexes of comb-shaped polyether and lithium aromatic sulfonates bearing different negative charge number were prepared by in situ thermal polymerization. Their conductivity depends deeply on salt content
ambient temperature and negative charge number of the added salts. Results show that anions can be partly immobilized by increasing their negative charges at lower temperature. Against discharge time the short circuit current of the battery (Li/complex film/Li
x
V
3
O
8
) is stabilized by increasing the anionic charge number of the complex.
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