The morphology of some polyetherester-ureas were studied by
13
C CP/MAS and
1
H wide-line NMR spectroscopy. It was found that the HDI and MDI based polymers have well crystallized hard segments
whereas the TDI and HMDI based ones have not. For HDI/MDI based polymers
the presented results suggest that the distribution of two kinds of hard segment units is mainly in a block form. The influences of the different hard segment and chain length on the mobility of the soft segment were also studied.
Abstract
The morphology of some polyetherester-ureas were studied by
13
C CP/MAS and
1
H wide-line NMR spectroscopy. It was found that the HDI and MDI based polymers have well crystallized hard segments
whereas the TDI and HMDI based ones have not. For HDI/MDI based polymers
the presented results suggest that the distribution of two kinds of hard segment units is mainly in a block form. The influences of the different hard segment and chain length on the mobility of the soft segment were also studied.
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