SYNTHETIC AND CATALYTIC PROPERTY STUDIES ON SILICA SUPPORTED BIS-(ACETYLACETONATO) COBALT(Ⅱ) COMPLEXES**
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SYNTHETIC AND CATALYTIC PROPERTY STUDIES ON SILICA SUPPORTED BIS-(ACETYLACETONATO) COBALT(Ⅱ) COMPLEXES**
SYNTHETIC AND CATALYTIC PROPERTY STUDIES ON SILICA SUPPORTED BIS-(ACETYLACETONATO) COBALT(Ⅱ) COMPLEXES**
高分子科学(英文版)1992年10卷第3期 页码:210-217
Affiliations:
1. Chemistry Department, Suzhou University, Suzhou) LU Yun and LIN Sicong
2. Suzhou University
3. Suzhou
4. Nanjing University
5. Nanjing
Author bio:
Funds:
DOI:
中图分类号:
纸质出版:1992-09-20
Accepted:
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[1]李小虎,陆云,林思聪.SYNTHETIC AND CATALYTIC PROPERTY STUDIES ON SILICA SUPPORTED BIS-(ACETYLACETONATO) COBALT(Ⅱ) COMPLEXES~(**)[J].Chinese Journal of Polymer Science,1992,{4}(03):210-217.
LI Xiaohu, LU Yun, LIN Sicong. SYNTHETIC AND CATALYTIC PROPERTY STUDIES ON SILICA SUPPORTED BIS-(ACETYLACETONATO) COBALT(Ⅱ) COMPLEXES**[J]. 1992, 10(3): 210-217.
[1]李小虎,陆云,林思聪.SYNTHETIC AND CATALYTIC PROPERTY STUDIES ON SILICA SUPPORTED BIS-(ACETYLACETONATO) COBALT(Ⅱ) COMPLEXES~(**)[J].Chinese Journal of Polymer Science,1992,{4}(03):210-217.DOI:
LI Xiaohu, LU Yun, LIN Sicong. SYNTHETIC AND CATALYTIC PROPERTY STUDIES ON SILICA SUPPORTED BIS-(ACETYLACETONATO) COBALT(Ⅱ) COMPLEXES**[J]. 1992, 10(3): 210-217.DOI:
SYNTHETIC AND CATALYTIC PROPERTY STUDIES ON SILICA SUPPORTED BIS-(ACETYLACETONATO) COBALT(Ⅱ) COMPLEXES**
<正> This paper reports mainly the preparation of silica supported acetylacetone ligands and their cobalt complexes
the characterization of their chemical structure
and the evaluation of their catalytic activity in the reaction for the preparation of ethers directly from alkanols and benzyl chloride. The results indicate that those silica supported β-diketone cobalt complexes (SACO) not only can simplify the reaction procedure of the ether preparation but also show a much higher catalytic activity in comparison with other homogeneous catalysts. In addition
SACO can be recovered and reused although their catalytic activity descend gradually as a result of the decrease in their cobalt content.
Abstract
This paper reports mainly the preparation of silica supported acetylacetone ligands and their cobalt complexes
the characterization of their chemical structure
and the evaluation of their catalytic activity in the reaction for the preparation of ethers directly from alkanols and benzyl chloride. The results indicate that those silica supported β-diketone cobalt complexes (SACO) not only can simplify the reaction procedure of the ether preparation but also show a much higher catalytic activity in comparison with other homogeneous catalysts. In addition
SACO can be recovered and reused although their catalytic activity descend gradually as a result of the decrease in their cobalt content.
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