STUDY ON POLYMER—Ru-Co—BIMETALLIC COMPLEXES CATALYSTS Ⅰ. SYNTHESIS OF CATALYSTS AND THEIR USE FOR THE HYDROFORMYLATION

TANG Qi; ZONG Huijuan; CHEN Zonghan; JIANG Yingyan

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STUDY ON POLYMER—Ru-Co—BIMETALLIC COMPLEXES CATALYSTS Ⅰ. SYNTHESIS OF CATALYSTS AND THEIR USE FOR THE HYDROFORMYLATION

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- STUDY ON POLYMER—Ru-Co—BIMETALLIC COMPLEXES CATALYSTS Ⅰ. SYNTHESIS OF CATALYSTS AND THEIR USE FOR THE HYDROFORMYLATION
- STUDY ON POLYMER—Ru-Co—BIMETALLIC COMPLEXES CATALYSTS Ⅰ. SYNTHESIS OF CATALYSTS AND THEIR USE FOR THE HYDROFORMYLATION
- 高分子科学（英文版） 1991年9卷第1期页码：39-47
- Affiliations：
  
  1. Department of Materials Science and Engineering, University of Science and Technology of China, Hefei, Anhui) CHEN Zonghan and JIANG Yingyan
  2. Academia Sinica
  3. Beijing
- Author bio：
- Funds：
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  中图分类号：
- 纸质出版：1991-03-20
- Accepted：
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[1]汤琪,宗惠娟,陈宗翰,江英彦.STUDY ON POLYMER—Ru-Co—BIMETALLIC COMPLEXES CATALYSTS Ⅰ. SYNTHESIS OF CATALYSTS AND THEIR USE FOR THE HYDROFORMYLATION[J].Chinese Journal of Polymer Science,1991,{4}(01):39-47.

TANG Qi, ZONG Huijuan, CHEN Zonghan, et al. STUDY ON POLYMER—Ru-Co—BIMETALLIC COMPLEXES CATALYSTS Ⅰ. SYNTHESIS OF CATALYSTS AND THEIR USE FOR THE HYDROFORMYLATION[J]. 1991, 9(1): 39-47.
[1]汤琪,宗惠娟,陈宗翰,江英彦.STUDY ON POLYMER—Ru-Co—BIMETALLIC COMPLEXES CATALYSTS Ⅰ. SYNTHESIS OF CATALYSTS AND THEIR USE FOR THE HYDROFORMYLATION[J].Chinese Journal of Polymer Science,1991,{4}(01):39-47. DOI：

TANG Qi, ZONG Huijuan, CHEN Zonghan, et al. STUDY ON POLYMER—Ru-Co—BIMETALLIC COMPLEXES CATALYSTS Ⅰ. SYNTHESIS OF CATALYSTS AND THEIR USE FOR THE HYDROFORMYLATION[J]. 1991, 9(1): 39-47. DOI：

摘要

正

Six kinds of polymer ligands

supported on SiO

containing coordinating atoms P

S and N respectively

have been synthesized. The Ru（Ⅲ）-Co（Ⅱ） bimetallic complexes of these polymer ligands have been obtained and examined as catalysts for the hydroformylation of cyclohexene. The effects of reaction temperature

pressure and Co/Ru ratio etc. on the activities of catalysts were investigated in detail. The catalysts are all polymer-noncarbonyl-metal complexes

easily to be prepared

active and stable. From the experimental results it can be suggested that under reaction conditions such polymer-noncarbonyl-metal complexes convert "in situ" to polymer-carbonyl-metal complexes

thus become active catalysts. The course of this conversion is supposed as a preliminary approach.

Abstract

Six kinds of polymer ligands

supported on SiO

containing coordinating atoms P

S and N respectively

pressure and Co/Ru ratio etc. on the activities of catalysts were investigated in detail. The catalysts are all polymer-noncarbonyl-metal complexes

easily to be prepared

active and stable. From the experimental results it can be suggested that under reaction conditions such polymer-noncarbonyl-metal complexes convert "in situ" to polymer-carbonyl-metal complexes

thus become active catalysts. The course of this conversion is supposed as a preliminary approach.

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