SYNTHESES OF THE SOLUBLE,HIGH MOLECULAR WEIGHT AND LADDERLIKE POLYPH ENYLSILSESQUIOXAN E AND COPOLYMETHYLPHENYLSILSESQUIOXANES BY PREAMMINOLYSIS METHOD

XIE Zusho; DAI Daorong; ZHANG Rongben

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SYNTHESES OF THE SOLUBLE,HIGH MOLECULAR WEIGHT AND LADDERLIKE POLYPH ENYLSILSESQUIOXAN E AND COPOLYMETHYLPHENYLSILSESQUIOXANES BY PREAMMINOLYSIS METHOD

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- SYNTHESES OF THE SOLUBLE,HIGH MOLECULAR WEIGHT AND LADDERLIKE POLYPH ENYLSILSESQUIOXAN E AND COPOLYMETHYLPHENYLSILSESQUIOXANES BY PREAMMINOLYSIS METHOD
- SYNTHESES OF THE SOLUBLE,HIGH MOLECULAR WEIGHT AND LADDERLIKE POLYPH ENYLSILSESQUIOXAN E AND COPOLYMETHYLPHENYLSILSESQUIOXANES BY PREAMMINOLYSIS METHOD
- 高分子科学（英文版） 1991年9卷第3期页码：266-272
- Affiliations：
  
  1. Institute of Chemistry, Academia Sinica,Beijing
  2. Academia Sinica
  3. Beijing
- Author bio：
- Funds：
- DOI：
  中图分类号：
- 纸质出版：1991-09-20
- Accepted：
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[1]谢祖(王寿),戴道荣,张榕本.SYNTHESES OF THE SOLUBLE,HIGH MOLECULAR WEIGHT AND LADDERLIKE POLYPH ENYLSILSESQUIOXAN E AND COPOLYMETHYLPHENYLSILSESQUIOXANES BY PREAMMINOLYSIS METHOD[J].Chinese Journal of Polymer Science,1991,{4}(03):266-272.

XIE Zusho, DAI Daorong, ZHANG Rongben. SYNTHESES OF THE SOLUBLE,HIGH MOLECULAR WEIGHT AND LADDERLIKE POLYPH ENYLSILSESQUIOXAN E AND COPOLYMETHYLPHENYLSILSESQUIOXANES BY PREAMMINOLYSIS METHOD[J]. 1991, 9(3): 266-272.
[1]谢祖(王寿),戴道荣,张榕本.SYNTHESES OF THE SOLUBLE,HIGH MOLECULAR WEIGHT AND LADDERLIKE POLYPH ENYLSILSESQUIOXAN E AND COPOLYMETHYLPHENYLSILSESQUIOXANES BY PREAMMINOLYSIS METHOD[J].Chinese Journal of Polymer Science,1991,{4}(03):266-272. DOI：

XIE Zusho, DAI Daorong, ZHANG Rongben. SYNTHESES OF THE SOLUBLE,HIGH MOLECULAR WEIGHT AND LADDERLIKE POLYPH ENYLSILSESQUIOXAN E AND COPOLYMETHYLPHENYLSILSESQUIOXANES BY PREAMMINOLYSIS METHOD[J]. 1991, 9(3): 266-272. DOI：

摘要

正

Soluble

high molecular weight （MW） and ladderlike polyphenylsilsesquioxane （LPPSQ） and its copolymers

ladderlike random and block copolymethyiphenylsilsesquioxanes（LR-PMPSQ and LB-PMPSQ）have been prepared by preamminolysis

hydrolysis and polycondensation reactions. The preparation method can be carried out easily at the temperature below 95℃with high yield of 95 %

instead of the conventional way by using high-boiling solvent and any reaction activator or by precipitation with methanol. Three kinds of ladderlike polymers have been characterized. The MW’s of the polymers reached to 10

without noticeable gelling. The scheme for synthetic route has been proposed.

Abstract

Soluble

high molecular weight （MW） and ladderlike polyphenylsilsesquioxane （LPPSQ） and its copolymers

ladderlike random and block copolymethyiphenylsilsesquioxanes（LR-PMPSQ and LB-PMPSQ）have been prepared by preamminolysis

hydrolysis and polycondensation reactions. The preparation method can be carried out easily at the temperature below 95℃ with high yield of 95 %

without noticeable gelling. The scheme for synthetic route has been proposed.

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