<正> The spatial distribution function and second moments of circular freely jointed chain are derived based on an analytical method. The circular Gauss chain
which is simple for long chains
is compared with the circular freely jointed chain
which is exact for short chains. It is shown that the Gauss chain model predicts a more compact configurational distribution than the exact freely jointed chain. The two chain models
however
become closer to each other when the chain length increases. It is found that the difference of the mean square radius of gyration calculated with these two chain models is a constant
independent of the chain length.
Abstract
The spatial distribution function and second moments of circular freely jointed chain are derived based on an analytical method. The circular Gauss chain
which is simple for long chains
is compared with the circular freely jointed chain
which is exact for short chains. It is shown that the Gauss chain model predicts a more compact configurational distribution than the exact freely jointed chain. The two chain models
however
become closer to each other when the chain length increases. It is found that the difference of the mean square radius of gyration calculated with these two chain models is a constant
independent of the chain length.
关键词
Keywords
references
The trial reading is over, you can activate your VIP account to continue reading.