HYDROFORMYLATION CATALYSIS USING POLYMER-SUPPORTED MULTINUCLEAR RHODIUM CARBONYL CLUSTER CATALYSTS*

HE Binlin; SUN Juntan; LI Hong; SANG Junjie

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HYDROFORMYLATION CATALYSIS USING POLYMER-SUPPORTED MULTINUCLEAR RHODIUM CARBONYL CLUSTER CATALYSTS*

Papers | Updated：2021-06-21

- HYDROFORMYLATION CATALYSIS USING POLYMER-SUPPORTED MULTINUCLEAR RHODIUM CARBONYL CLUSTER CATALYSTS*
- HYDROFORMYLATION CATALYSIS USING POLYMER-SUPPORTED MULTINUCLEAR RHODIUM CARBONYL CLUSTER CATALYSTS*
- 高分子科学（英文版） 1990年8卷第2期页码：158-164
- Affiliations：
  
  1. Institute of Polymer Chemistry, Nankai University,Tianjin
  2. Nankai University
  3. Tianjin
- Author bio：
- Funds：
- DOI：
  中图分类号：
- 纸质出版：1990-06-20
- Accepted：
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[1]何炳林,孙君坦,李弘,桑俊杰.HYDROFORMYLATION CATALYSIS USING POLYMER-SUPPORTED MULTINUCLEAR RHODIUM CARBONYL CLUSTER CATALYSTS[J].Chinese Journal of Polymer Science,1990,{4}(02):158-164.

HE Binlin, SUN Juntan, LI Hong, et al. HYDROFORMYLATION CATALYSIS USING POLYMER-SUPPORTED MULTINUCLEAR RHODIUM CARBONYL CLUSTER CATALYSTS*[J]. 1990, 8(2): 158-164.
[1]何炳林,孙君坦,李弘,桑俊杰.HYDROFORMYLATION CATALYSIS USING POLYMER-SUPPORTED MULTINUCLEAR RHODIUM CARBONYL CLUSTER CATALYSTS[J].Chinese Journal of Polymer Science,1990,{4}(02):158-164. DOI：

HE Binlin, SUN Juntan, LI Hong, et al. HYDROFORMYLATION CATALYSIS USING POLYMER-SUPPORTED MULTINUCLEAR RHODIUM CARBONYL CLUSTER CATALYSTS*[J]. 1990, 8(2): 158-164. DOI：

摘要

正

A series of polymer-supported tetranuclear rhodium carbonyl cluster catalysts were prepared b the reaction of Rh

（CO）

with several kinds of polymer supports such as crosslinked poly （N-vinylpyrrolidone）（PNVP） and crosslinked poly （ styrene-co-maleic anhydride）（PMAn）

and subsequently were used to catalyze the hydroformylation of olefins. The catalysts were characterized by IR

SEM and XPS. The influence of the supports structure and crosslinking

metal’s content and particle size of the supports on the catalysts hydroformylation properties was studied. The factors which affect the catalytic conversion were also examined. The experimental results show that the polymer-supported Rh cluster catalysts possess very high catalytic activity and aldehyde selectivity as well as good reproducibility.

Abstract

A series of polymer-supported tetranuclear rhodium carbonyl cluster catalysts were prepared b the reaction of Rh

（CO）

with several kinds of polymer supports such as crosslinked poly （N-vinylpyrrolidone）（PNVP） and crosslinked poly （ styrene-co-maleic anhydride）（PMAn）

and subsequently were used to catalyze the hydroformylation of olefins. The catalysts were characterized by IR

SEM and XPS. The influence of the supports structure and crosslinking

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