AROMATIC AND HETEROCYCLIC NITRILES AND THEIR POLYMERS ⅩⅥ. THE POLYMERIZATION KINETICS OF 4, 4′-BIPHENYLDICARBONITRILE CATALYZED BY LEWIS ACID-METAL SYSTEM

SUN Luying; HUANG Zhitang

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AROMATIC AND HETEROCYCLIC NITRILES AND THEIR POLYMERS ⅩⅥ. THE POLYMERIZATION KINETICS OF 4, 4′-BIPHENYLDICARBONITRILE CATALYZED BY LEWIS ACID-METAL SYSTEM

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- AROMATIC AND HETEROCYCLIC NITRILES AND THEIR POLYMERS ⅩⅥ. THE POLYMERIZATION KINETICS OF 4, 4′-BIPHENYLDICARBONITRILE CATALYZED BY LEWIS ACID-METAL SYSTEM
- AROMATIC AND HETEROCYCLIC NITRILES AND THEIR POLYMERS ⅩⅥ. THE POLYMERIZATION KINETICS OF 4, 4′-BIPHENYLDICARBONITRILE CATALYZED BY LEWIS ACID-METAL SYSTEM
- 高分子科学（英文版） 1990年8卷第2期页码：177-182
- Affiliations：
  
  1. Institute of Chemistry, Academia Sinica,Beijing
  2. Academia Sinica
  3. Beijing
- Author bio：
- Funds：
- DOI：
  中图分类号：
- 纸质出版：1990-06-20
- Accepted：
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[1]孙录应,黄志镗.AROMATIC AND HETEROCYCLIC NITRILES AND THEIR POLYMERS ⅩⅥ. THE POLYMERIZATION KINETICS OF 4, 4′-BIPHENYLDICARBONITRILE CATALYZED BY LEWIS ACID-METAL SYSTEM[J].Chinese Journal of Polymer Science,1990,{4}(02):177-182.

SUN Luying, HUANG Zhitang. AROMATIC AND HETEROCYCLIC NITRILES AND THEIR POLYMERS ⅩⅥ. THE POLYMERIZATION KINETICS OF 4, 4′-BIPHENYLDICARBONITRILE CATALYZED BY LEWIS ACID-METAL SYSTEM[J]. 1990, 8(2): 177-182.
[1]孙录应,黄志镗.AROMATIC AND HETEROCYCLIC NITRILES AND THEIR POLYMERS ⅩⅥ. THE POLYMERIZATION KINETICS OF 4, 4′-BIPHENYLDICARBONITRILE CATALYZED BY LEWIS ACID-METAL SYSTEM[J].Chinese Journal of Polymer Science,1990,{4}(02):177-182. DOI：

SUN Luying, HUANG Zhitang. AROMATIC AND HETEROCYCLIC NITRILES AND THEIR POLYMERS ⅩⅥ. THE POLYMERIZATION KINETICS OF 4, 4′-BIPHENYLDICARBONITRILE CATALYZED BY LEWIS ACID-METAL SYSTEM[J]. 1990, 8(2): 177-182. DOI：

摘要

<正> The polymerization kinetics of 4

4′-biphenyldicarbonitrile using cuprous chloride-zinc system as catatyst was investigated. the concentration of unreacted cyano group was measured by infrared spectroscopic analysis using potassium ferricyanide as the internal reference. It was found that the polymerization rate is directly proportional to the concentrations ofcyano group

cuprous chloride and zinc

and the activation energy of the polymerization is as Tow as 18.4 KJ/mol. In addition

the other kinetics parameters were obtained and discussed.

Abstract

The polymerization kinetics of 4

cuprous chloride and zinc

and the activation energy of the polymerization is as Tow as 18.4 KJ/mol. In addition

the other kinetics parameters were obtained and discussed.

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