STUDIES ON ORGANIC PEROXIDE/N, NDI (2-α-METHYL-ACRYLOYLOXY PROPYL)-PARA-TOLUIDINE BINARY SYSTEMS

QIU Kunyuan; FU Jie GUO; Xinqiu; FENG Xinde

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STUDIES ON ORGANIC PEROXIDE/N, NDI (2-α-METHYL-ACRYLOYLOXY PROPYL)-PARA-TOLUIDINE BINARY SYSTEMS

Papers | Updated：2021-06-21

- STUDIES ON ORGANIC PEROXIDE/N, NDI (2-α-METHYL-ACRYLOYLOXY PROPYL)-PARA-TOLUIDINE BINARY SYSTEMS
- STUDIES ON ORGANIC PEROXIDE/N, NDI (2-α-METHYL-ACRYLOYLOXY PROPYL)-PARA-TOLUIDINE BINARY SYSTEMS
- 高分子科学（英文版） 1990年8卷第2期页码：188-195
- Affiliations：
  
  1. Department of Chemistry, Peking University,Beijing
  2. Peking University
  3. Beijing
- Author bio：
- Funds：
- DOI：
  中图分类号：
- 纸质出版：1990-06-20
- Accepted：
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[1]丘坤元,傅杰,郭新秋,冯新德.STUDIES ON ORGANIC PEROXIDE/N, NDI(2-α-METHYL-ACRYLOYLOXY PROPYL)-PARA-TOLUIDINE BINARY SYSTEMS[J].Chinese Journal of Polymer Science,1990,{4}(02):188-195.

QIU Kunyuan, FU Jie GUO, Xinqiu, et al. STUDIES ON ORGANIC PEROXIDE/N, NDI (2-α-METHYL-ACRYLOYLOXY PROPYL)-PARA-TOLUIDINE BINARY SYSTEMS[J]. 1990, 8(2): 188-195.
[1]丘坤元,傅杰,郭新秋,冯新德.STUDIES ON ORGANIC PEROXIDE/N, NDI(2-α-METHYL-ACRYLOYLOXY PROPYL)-PARA-TOLUIDINE BINARY SYSTEMS[J].Chinese Journal of Polymer Science,1990,{4}(02):188-195. DOI：

QIU Kunyuan, FU Jie GUO, Xinqiu, et al. STUDIES ON ORGANIC PEROXIDE/N, NDI (2-α-METHYL-ACRYLOYLOXY PROPYL)-PARA-TOLUIDINE BINARY SYSTEMS[J]. 1990, 8(2): 188-195. DOI：

摘要

正

The polymerization of methyl methacrylate （MMA） initiated by organic peroxide and polymerizable aromatic tertiary amine such as N

N-di （2-α-methylacryloyloxy propyl）-p-toluidine （MP）

PT binary system has been studied. It was found that the （MP）

PT promotes MMA polymerization

and the kinetics of MMA polymerization fits the radical polymerization rate equation. Based on the ESR studies and the end-group analysis the initiation mechanism is proposed.

Abstract

The polymerization of methyl methacrylate （MMA） initiated by organic peroxide and polymerizable aromatic tertiary amine such as N

N-di （2-α-methylacryloyloxy propyl）-p-toluidine （MP）

PT binary system has been studied. It was found that the （MP）

PT promotes MMA polymerization

and the kinetics of MMA polymerization fits the radical polymerization rate equation. Based on the ESR studies and the end-group analysis the initiation mechanism is proposed.

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