AROMATIC AND HETEROCYCLIC NITRILES AND THEIR POLYMERS ⅩⅦ. THE POLYMERIZATION KINETICS OF CYANOPYRIDINES AND CHARACTERIZATION OF THE FORMED POLYMER*

SUN Luying; HUANG Zhitang

Your Location：

Home >

Browse articles >

AROMATIC AND HETEROCYCLIC NITRILES AND THEIR POLYMERS ⅩⅦ. THE POLYMERIZATION KINETICS OF CYANOPYRIDINES AND CHARACTERIZATION OF THE FORMED POLYMER*

Papers | Updated：2021-06-21

- AROMATIC AND HETEROCYCLIC NITRILES AND THEIR POLYMERS ⅩⅦ. THE POLYMERIZATION KINETICS OF CYANOPYRIDINES AND CHARACTERIZATION OF THE FORMED POLYMER*
- AROMATIC AND HETEROCYCLIC NITRILES AND THEIR POLYMERS ⅩⅦ. THE POLYMERIZATION KINETICS OF CYANOPYRIDINES AND CHARACTERIZATION OF THE FORMED POLYMER*
- 高分子科学（英文版） 1990年8卷第4期页码：371-376
- Affiliations：
  
  1. Institute of Chemistry, Academia Sinica,Beijing
  2. Academia Sinica
  3. Academia Sinica Beijing
- Author bio：
- Funds：
- DOI：
  中图分类号：
- 纸质出版：1990-12-20
- Accepted：
Scan QR Code
[1]孙录应,黄志镗.AROMATIC AND HETEROCYCLIC NITRILES AND THEIR POLYMERS ⅩⅦ. THE POLYMERIZATION KINETICS OF CYANOPYRIDINES AND CHARACTERIZATION OF THE FORMED POLYMER[J].Chinese Journal of Polymer Science,1990,{4}(04):371-376.

SUN Luying, HUANG Zhitang. AROMATIC AND HETEROCYCLIC NITRILES AND THEIR POLYMERS ⅩⅦ. THE POLYMERIZATION KINETICS OF CYANOPYRIDINES AND CHARACTERIZATION OF THE FORMED POLYMER*[J]. 1990, 8(4): 371-376.
[1]孙录应,黄志镗.AROMATIC AND HETEROCYCLIC NITRILES AND THEIR POLYMERS ⅩⅦ. THE POLYMERIZATION KINETICS OF CYANOPYRIDINES AND CHARACTERIZATION OF THE FORMED POLYMER[J].Chinese Journal of Polymer Science,1990,{4}(04):371-376. DOI：

SUN Luying, HUANG Zhitang. AROMATIC AND HETEROCYCLIC NITRILES AND THEIR POLYMERS ⅩⅦ. THE POLYMERIZATION KINETICS OF CYANOPYRIDINES AND CHARACTERIZATION OF THE FORMED POLYMER*[J]. 1990, 8(4): 371-376. DOI：

摘要

正

The polymerization rates of three cyanopyridines catalyzed by cuprous chloride-zinc system are measured

and the structure of the formed polymer is also determined. Compared with aromatic nitrile

cyanopyridines polymerize faster and form polyconjugated polymer with skeleton—（C=N）—

instead of triazine structure. This chain-polymer possesses semiconductive property

and can be converted into conductive material by thermal treatment. In addition

the polymerization kinetics of 3-cyanopyridine catalyzed by 3-cyanopyridinium perchlorate is investigated. It is found that the polymerization rate is directly proportional to the concentrations of monomer and catalyst

and the activation energy of the polymerization is 103.1 KJ/mol.

Abstract

The polymerization rates of three cyanopyridines catalyzed by cuprous chloride-zinc system are measured

and the structure of the formed polymer is also determined. Compared with aromatic nitrile

cyanopyridines polymerize faster and form polyconjugated polymer with skeleton—（C=N）—

instead of triazine structure. This chain-polymer possesses semiconductive property

and can be converted into conductive material by thermal treatment. In addition

and the activation energy of the polymerization is 103.1 KJ/mol.

关键词

Keywords

references

浏览量

Downloads

CSCD

文章被引用时，请邮件提醒。

Submit

工具集

关联资源

Epoxy-functionalized Cyclohexane-based Ricinoleate Plasticizer: Synthesis, Performance Evaluation, and Plasticizing Mechanism

Enhanced Segment Mobility Promotes Stereocomplex Crystallization in Polymer Blends via Elevated Segmental Miscibility

Tunable Circularly Polarized Luminescence of Helical Poly(phenylacetylene)s via Side-chain-to-Backbone Förster Resonance Energy Transfer

pH-Responsive L-Cysteine-conjugated Polydopamine Nanocarriers for Controlled Release of Emamectin Benzoate against Pieris brassicae

End-to-End Neuron-inspired Signal Transduction Using Organic Electrochemical Transistors