A NOVEL COPOLYMER-BOUND CIS-DICARBONYLRHODIUM COMPLEX FOR THE CARBONYLATION OF METHANOL TO ACETIC ACID AND ACETIC ANHYDRIDE

YUAN Guoqing; CHEN Yuying; CHEN Rongyao

Your Location：

Home >

Browse articles >

A NOVEL COPOLYMER-BOUND CIS-DICARBONYLRHODIUM COMPLEX FOR THE CARBONYLATION OF METHANOL TO ACETIC ACID AND ACETIC ANHYDRIDE

Papers | Updated：2021-06-21

- A NOVEL COPOLYMER-BOUND CIS-DICARBONYLRHODIUM COMPLEX FOR THE CARBONYLATION OF METHANOL TO ACETIC ACID AND ACETIC ANHYDRIDE
- A NOVEL COPOLYMER-BOUND CIS-DICARBONYLRHODIUM COMPLEX FOR THE CARBONYLATION OF METHANOL TO ACETIC ACID AND ACETIC ANHYDRIDE
- 高分子科学（英文版） 1989年7卷第3期页码：219-224
- Affiliations：
  
  1. Institute of Chemistry, Academia Sinica,Beijing
  2. Academia Sinica
  3. Beijing
- Author bio：
- Funds：
- DOI：
  中图分类号：
- 纸质出版：1989-09-20
- Accepted：
Scan QR Code
[1]袁国卿,陈予英,陈荣耀.A NOVEL COPOLYMER-BOUND CIS-DICARBONYLRHODIUM COMPLEX FOR THE CARBONYLATION OF METHANOL TO ACETIC ACID AND ACETIC ANHYDRIDE[J].Chinese Journal of Polymer Science,1989,{4}(03):219-224.

YUAN Guoqing, CHEN Yuying, CHEN Rongyao. A NOVEL COPOLYMER-BOUND CIS-DICARBONYLRHODIUM COMPLEX FOR THE CARBONYLATION OF METHANOL TO ACETIC ACID AND ACETIC ANHYDRIDE[J]. 1989, 7(3): 219-224.
[1]袁国卿,陈予英,陈荣耀.A NOVEL COPOLYMER-BOUND CIS-DICARBONYLRHODIUM COMPLEX FOR THE CARBONYLATION OF METHANOL TO ACETIC ACID AND ACETIC ANHYDRIDE[J].Chinese Journal of Polymer Science,1989,{4}(03):219-224. DOI：

YUAN Guoqing, CHEN Yuying, CHEN Rongyao. A NOVEL COPOLYMER-BOUND CIS-DICARBONYLRHODIUM COMPLEX FOR THE CARBONYLATION OF METHANOL TO ACETIC ACID AND ACETIC ANHYDRIDE[J]. 1989, 7(3): 219-224. DOI：

摘要

<正> A series of porous microspheres of linear and ethylene diacrylate （M’） cross-linked copolymers of 2-vinylpyridine （V） and methyl acrylate （M） reacted with tetracarbonyldichlorodirhodium to form a series of cis-dicarbonylrhodium chelate complex （MVRh and MVM ’Rh）. They are thermally stable yet very reactive in the carbonylation of methanol to acetic acid

and of methanol-acetic acid mixture to acetic acid and acetic anhydride with a selectivity of 100% under relatively mild and anhydrous conditions.

Abstract

A series of porous microspheres of linear and ethylene diacrylate （M’） cross-linked copolymers of 2-vinylpyridine （V） and methyl acrylate （M） reacted with tetracarbonyldichlorodirhodium to form a series of cis-dicarbonylrhodium chelate complex （MVRh and MVM ’Rh）. They are thermally stable yet very reactive in the carbonylation of methanol to acetic acid

and of methanol-acetic acid mixture to acetic acid and acetic anhydride with a selectivity of 100% under relatively mild and anhydrous conditions.

关键词

Keywords

references

浏览量

234

Downloads

CSCD

文章被引用时，请邮件提醒。

Submit

工具集

关联资源

One-handed Helical Poly(m-terphenyl acetylene)s with Broad Optical Activity Range from Ultraviolet-Visible to Near-infrared Regions

Bioinspired Zinc-doped Nano Hydroxyapatite Reinforced Poly(lactic acid) Composites for Bone Repair

A Paradigm for BF3 Co-initiated Cationic Polymerization with Low Dispersity: Introducing Acetonitrile and Lowering the Reaction Temperature

Silk Sericin-inspired Poly-β-homoserine for Protein Protection

End-group and Side-chain Dual-engineering of Selenium-fused Acceptors for 20.08% Efficiency Polymer Solar Cells with Low Energy Loss