SYNTHESIS AND FREE RADICAL RING-OPENING POLYMERIZATION OF 2-METHYL-AND 2-METHYL-9-n-BUTYL-(-7-METHYLENE-1,4,6-TRIOXA-SPIRO (4, 4)NONANE)*

PAN Caiyuan; WANG Yin

Your Location：

Home >

Browse articles >

SYNTHESIS AND FREE RADICAL RING-OPENING POLYMERIZATION OF 2-METHYL-AND 2-METHYL-9-n-BUTYL-(-7-METHYLENE-1,4,6-TRIOXA-SPIRO (4, 4)NONANE)*

Papers | Updated：2021-06-21

- SYNTHESIS AND FREE RADICAL RING-OPENING POLYMERIZATION OF 2-METHYL-AND 2-METHYL-9-n-BUTYL-(-7-METHYLENE-1,4,6-TRIOXA-SPIRO (4, 4)NONANE)*
- SYNTHESIS AND FREE RADICAL RING-OPENING POLYMERIZATION OF 2-METHYL-AND 2-METHYL-9-n-BUTYL-(-7-METHYLENE-1,4,6-TRIOXA-SPIRO (4, 4)NONANE)*
- 高分子科学（英文版） 1989年7卷第3期页码：232-238
- Affiliations：
  
  1. Department of Materials Science and Engineering. Vniversity of Science and Technoloy of China,Hefei
  2. University of Science and Technology of China. Hefei
- Author bio：
- Funds：
- DOI：
  中图分类号：
- 纸质出版：1989-09-20
- Accepted：
Scan QR Code
[1]潘才元,王寅.SYNTHESIS AND FREE RADICAL RING-OPENING POLYMERIZATION OF 2-METHYL-AND 2-METHYL-9-n-BUTYL-(-7-METHYLENE-1,4,6-TRIOXA-SPIRO (4, 4)NONANE)[J].Chinese Journal of Polymer Science,1989,{4}(03):232-238.

PAN Caiyuan, WANG Yin. SYNTHESIS AND FREE RADICAL RING-OPENING POLYMERIZATION OF 2-METHYL-AND 2-METHYL-9-n-BUTYL-(-7-METHYLENE-1,4,6-TRIOXA-SPIRO (4, 4)NONANE)*[J]. 1989, 7(3): 232-238.
[1]潘才元,王寅.SYNTHESIS AND FREE RADICAL RING-OPENING POLYMERIZATION OF 2-METHYL-AND 2-METHYL-9-n-BUTYL-(-7-METHYLENE-1,4,6-TRIOXA-SPIRO (4, 4)NONANE)[J].Chinese Journal of Polymer Science,1989,{4}(03):232-238. DOI：

PAN Caiyuan, WANG Yin. SYNTHESIS AND FREE RADICAL RING-OPENING POLYMERIZATION OF 2-METHYL-AND 2-METHYL-9-n-BUTYL-(-7-METHYLENE-1,4,6-TRIOXA-SPIRO (4, 4)NONANE)*[J]. 1989, 7(3): 232-238. DOI：

摘要

正

This paper describes the synthesis and free radical ring-opening polymerization of 2-methyl-and 2-methyl-9-n-butyl （-7-methylene-1

6-trioxaspiro （4

4） nonane）. The structures of the two polymers were verified by IR

’H and

C NMR spectra. The substituent on 9-position of 7-methylene-trioxaspiro （4

4） nonane affects the structure of polymer and polymerization activity. The polymerization mechanism is discussed.

Abstract

This paper describes the synthesis and free radical ring-opening polymerization of 2-methyl-and 2-methyl-9-n-butyl （-7-methylene-1

6-trioxaspiro （4

4） nonane）. The structures of the two polymers were verified by IR

’H and

C NMR spectra. The substituent on 9-position of 7-methylene-trioxaspiro （4

4） nonane affects the structure of polymer and polymerization activity. The polymerization mechanism is discussed.

关键词

Keywords

references

浏览量

175

Downloads

CSCD

文章被引用时，请邮件提醒。

Submit

工具集

关联资源

Topology-regulated Co-assembly of Single Chain Polymer Nanoparticles and Block Copolymers into Hierarchical Micelle@Vesicle Composite Structures

On-demand Peelable UV-curable Adhesives with Superior Bonding Strength: Rational Molecular Engineering of Cohesion-adhesion Synergy

End-to-End Neuron-inspired Signal Transduction Using Organic Electrochemical Transistors

Improvements of Hydrophobicity and Toughness of Epoxy Coatings Modified with Hydroxyl-terminated Fluororubber

Upgrading Commercially Available Polyethylene to High-value Materials with Strong Mechanical Performance and Hydrophilicity by Blending with Ethylene/meta-Methoxystyrene Copolymers