THE BIMODAL MOLECULAR WEIGHT DISTRIBUTION OF cis-POLYBUTADIENE POLYMERIZED WITH LANTHANIDE COMPLEX CATALYSTS

CHENG Rongshi; HU Huizhen; JIANG Liansheng

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THE BIMODAL MOLECULAR WEIGHT DISTRIBUTION OF cis-POLYBUTADIENE POLYMERIZED WITH LANTHANIDE COMPLEX CATALYSTS

Papers | Updated：2021-06-21

- THE BIMODAL MOLECULAR WEIGHT DISTRIBUTION OF cis-POLYBUTADIENE POLYMERIZED WITH LANTHANIDE COMPLEX CATALYSTS
- THE BIMODAL MOLECULAR WEIGHT DISTRIBUTION OF cis-POLYBUTADIENE POLYMERIZED WITH LANTHANIDE COMPLEX CATALYSTS
- 高分子科学（英文版） 1987年5卷第2期页码：101-108
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- 纸质出版：1987-06-20
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CHENG Rongshi, HU Huizhen, JIANG Liansheng. THE BIMODAL MOLECULAR WEIGHT DISTRIBUTION OF cis-POLYBUTADIENE POLYMERIZED WITH LANTHANIDE COMPLEX CATALYSTS[J]. 高分子科学（英文版）, 1987,5(2):101-108.

CHENG Rongshi, HU Huizhen, JIANG Liansheng. THE BIMODAL MOLECULAR WEIGHT DISTRIBUTION OF cis-POLYBUTADIENE POLYMERIZED WITH LANTHANIDE COMPLEX CATALYSTS[J]. 1987, 5(2): 101-108.
CHENG Rongshi, HU Huizhen, JIANG Liansheng. THE BIMODAL MOLECULAR WEIGHT DISTRIBUTION OF cis-POLYBUTADIENE POLYMERIZED WITH LANTHANIDE COMPLEX CATALYSTS[J]. 高分子科学（英文版）, 1987,5(2):101-108. DOI：

CHENG Rongshi, HU Huizhen, JIANG Liansheng. THE BIMODAL MOLECULAR WEIGHT DISTRIBUTION OF cis-POLYBUTADIENE POLYMERIZED WITH LANTHANIDE COMPLEX CATALYSTS[J]. 1987, 5(2): 101-108. DOI：

摘要

The variation of the molecular weight and molecular weight distribution of cis-polybutadiene in the course of polymerization catalyzed by lanthanide complex composed of triisobutyl aluminium or diisobutyl aluminium hydride was investigated by osmometry

viscometry and size exclusion chromatography. By analyzing the experimental data

the reasons of the appearance of himodal molecular weight distribution were elucidated and the possible mechanisms of polymerization were discussed.

Abstract

viscometry and size exclusion chromatography. By analyzing the experimental data

the reasons of the appearance of himodal molecular weight distribution were elucidated and the possible mechanisms of polymerization were discussed.

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