EFFECTS OF SOLVENT POLARITY ON FREE RADICAL COPOLY MERIZATION OF 5-HEXENOIC ACID AND ACRYLONITRILE

WANG Bing; XIE Shishan; CAO Mengjiun

Your Location：

Home >

Browse articles >

EFFECTS OF SOLVENT POLARITY ON FREE RADICAL COPOLY MERIZATION OF 5-HEXENOIC ACID AND ACRYLONITRILE

Papers | Updated：2021-06-21

- EFFECTS OF SOLVENT POLARITY ON FREE RADICAL COPOLY MERIZATION OF 5-HEXENOIC ACID AND ACRYLONITRILE
- EFFECTS OF SOLVENT POLARITY ON FREE RADICAL COPOLY MERIZATION OF 5-HEXENOIC ACID AND ACRYLONITRILE
- 高分子科学（英文版） 1987年5卷第2期页码：141-148
- Affiliations：
- Author bio：
- Funds：
- DOI：
  中图分类号：
- 纸质出版：1987-06-20
- Accepted：
Scan QR Code
WANG Bing, XIE Shishan, CAO Mengjiun. EFFECTS OF SOLVENT POLARITY ON FREE RADICAL COPOLY MERIZATION OF 5-HEXENOIC ACID AND ACRYLONITRILE[J]. 高分子科学（英文版）, 1987,5(2):141-148.

WANG Bing, XIE Shishan, CAO Mengjiun. EFFECTS OF SOLVENT POLARITY ON FREE RADICAL COPOLY MERIZATION OF 5-HEXENOIC ACID AND ACRYLONITRILE[J]. 1987, 5(2): 141-148.
WANG Bing, XIE Shishan, CAO Mengjiun. EFFECTS OF SOLVENT POLARITY ON FREE RADICAL COPOLY MERIZATION OF 5-HEXENOIC ACID AND ACRYLONITRILE[J]. 高分子科学（英文版）, 1987,5(2):141-148. DOI：

WANG Bing, XIE Shishan, CAO Mengjiun. EFFECTS OF SOLVENT POLARITY ON FREE RADICAL COPOLY MERIZATION OF 5-HEXENOIC ACID AND ACRYLONITRILE[J]. 1987, 5(2): 141-148. DOI：

摘要

The effects of solvent polarity on free radical copolymerization of 5-hexenoie acid and acrylonitrile at 60℃ were studied. It was observed thatas the polarity of solvents enhanced

both the copolymcrization rate and the reactivity ratios r1

r2 increased

while the alternating tendency of monomer units in copolymer chain decreased. It is believed that the solvent polarity raises the reactivities of acrylonitrile monomer and its growing chain radical

but causes no distinct variation in those of 5-hexenoic acid.

Abstract

The effects of solvent polarity on free radical copolymerization of 5-hexenoie acid and acrylonitrile at 60℃ were studied. It was observed thatas the polarity of solvents enhanced

both the copolymcrization rate and the reactivity ratios r1

r2 increased

while the alternating tendency of monomer units in copolymer chain decreased. It is believed that the solvent polarity raises the reactivities of acrylonitrile monomer and its growing chain radical

but causes no distinct variation in those of 5-hexenoic acid.

关键词

Keywords

references

浏览量

Downloads

CSCD

文章被引用时，请邮件提醒。

Submit

工具集

关联资源

Improvements of Hydrophobicity and Toughness of Epoxy Coatings Modified with Hydroxyl-terminated Fluororubber

Manipulating Hierarchical Aggregation Structure via Film-forming Kinetics Enables Organic Photovoltaics over 20% Efficiency

Pyrimidoisoindigo-based Polymers for Ambipolar Charge Transport

End-group and Side-chain Dual-engineering of Selenium-fused Acceptors for 20.08% Efficiency Polymer Solar Cells with Low Energy Loss

Tunable Circularly Polarized Luminescence of Helical Poly(phenylacetylene)s via Side-chain-to-Backbone Förster Resonance Energy Transfer