THE POLYMERIZATION OF d-ELEOSTEARIC ACID IN THE DIPALMITOYLPHOSPHATIDYLCHOLINE-α-ELEOSTEARIC ACID LIPOSOME*
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THE POLYMERIZATION OF d-ELEOSTEARIC ACID IN THE DIPALMITOYLPHOSPHATIDYLCHOLINE-α-ELEOSTEARIC ACID LIPOSOME*
THE POLYMERIZATION OF d-ELEOSTEARIC ACID IN THE DIPALMITOYLPHOSPHATIDYLCHOLINE-α-ELEOSTEARIC ACID LIPOSOME*
高分子科学(英文版)1986年4卷第4期 页码:346-352
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纸质出版:1986-12-20
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FANG Yifei. THE POLYMERIZATION OF d-ELEOSTEARIC ACID IN THE DIPALMITOYLPHOSPHATIDYLCHOLINE-α-ELEOSTEARIC ACID LIPOSOME*[J]. 高分子科学(英文版), 1986,4(4):346-352.
FANG Yifei. THE POLYMERIZATION OF d-ELEOSTEARIC ACID IN THE DIPALMITOYLPHOSPHATIDYLCHOLINE-α-ELEOSTEARIC ACID LIPOSOME*[J]. 1986, 4(4): 346-352.
FANG Yifei. THE POLYMERIZATION OF d-ELEOSTEARIC ACID IN THE DIPALMITOYLPHOSPHATIDYLCHOLINE-α-ELEOSTEARIC ACID LIPOSOME*[J]. 高分子科学(英文版), 1986,4(4):346-352.DOI:
FANG Yifei. THE POLYMERIZATION OF d-ELEOSTEARIC ACID IN THE DIPALMITOYLPHOSPHATIDYLCHOLINE-α-ELEOSTEARIC ACID LIPOSOME*[J]. 1986, 4(4): 346-352.DOI:
THE POLYMERIZATION OF d-ELEOSTEARIC ACID IN THE DIPALMITOYLPHOSPHATIDYLCHOLINE-α-ELEOSTEARIC ACID LIPOSOME*
The polymerization of α-eleostearic acid (α-ESA) in the dipalmitoylphosphatidylcholine (DPPC)-α-ESA liposome was studied. The polymerization was carried out by UV irradiation and was kineticfirst order. The rate constant depends on the ratio of DPPC to α-ESA in the liposome. A transitionpoint of reaction rate could be observed in the course of the polymerization
and it appearedearlier with elevated temperature. Before the transition point
the higher the DPPC to α-ESAratio the higher was the reaction rate;while after the transition point
the higher the DPPC to α-ESA ratio the lower was the reaction rate.
Abstract
The polymerization of α-eleostearic acid (α-ESA) in the dipalmitoylphosphatidylcholine (DPPC)-α-ESA liposome was studied. The polymerization was carried out by UV irradiation and was kineticfirst order. The rate constant depends on the ratio of DPPC to α-ESA in the liposome. A transitionpoint of reaction rate could be observed in the course of the polymerization
and it appearedearlier with elevated temperature. Before the transition point
the higher the DPPC to α-ESAratio the higher was the reaction rate;while after the transition point
the higher the DPPC to α-ESA ratio the lower was the reaction rate.
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