STUDY ON LONG CHAIN BRANCHING IN POLYBUTADIENES BY GPC COUPLED WITH CAPILLARY VISCOMETER
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STUDY ON LONG CHAIN BRANCHING IN POLYBUTADIENES BY GPC COUPLED WITH CAPILLARY VISCOMETER
STUDY ON LONG CHAIN BRANCHING IN POLYBUTADIENES BY GPC COUPLED WITH CAPILLARY VISCOMETER
高分子科学(英文版)1986年4卷第2期 页码:126-133
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纸质出版:1986-06-20
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JIN Chunshan, SUN Shulian, HOU Rencai, 等. STUDY ON LONG CHAIN BRANCHING IN POLYBUTADIENES BY GPC COUPLED WITH CAPILLARY VISCOMETER[J]. 高分子科学(英文版), 1986,4(2):126-133.
JIN Chunshan, SUN Shulian, HOU Rencai, et al. STUDY ON LONG CHAIN BRANCHING IN POLYBUTADIENES BY GPC COUPLED WITH CAPILLARY VISCOMETER[J]. 1986, 4(2): 126-133.
JIN Chunshan, SUN Shulian, HOU Rencai, 等. STUDY ON LONG CHAIN BRANCHING IN POLYBUTADIENES BY GPC COUPLED WITH CAPILLARY VISCOMETER[J]. 高分子科学(英文版), 1986,4(2):126-133.DOI:
JIN Chunshan, SUN Shulian, HOU Rencai, et al. STUDY ON LONG CHAIN BRANCHING IN POLYBUTADIENES BY GPC COUPLED WITH CAPILLARY VISCOMETER[J]. 1986, 4(2): 126-133.DOI:
STUDY ON LONG CHAIN BRANCHING IN POLYBUTADIENES BY GPC COUPLED WITH CAPILLARY VISCOMETER
The long chain branching of polybutadienes (PB) was measured with gel permeation chroma-tography coupled to an automatically recording capillary viscometer. In this method the experimentalrelation [η] (V) was translated into the calibration curve [η] (VR) for the monodisperse species. The curve is combined with the universal calibration so that the molecular weight distributionand an additional parameter
e.g. the average branching factor of this samples may be obtained. Longchain branching molecular weight changes with polymerization conditions.
Abstract
The long chain branching of polybutadienes (PB) was measured with gel permeation chroma-tography coupled to an automatically recording capillary viscometer. In this method the experimentalrelation [η] (V) was translated into the calibration curve [η] (VR) for the monodisperse species. The curve is combined with the universal calibration so that the molecular weight distributionand an additional parameter
e.g. the average branching factor of this samples may be obtained. Longchain branching molecular weight changes with polymerization conditions.
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