SYNTHESIS AND POLYMERIZATION OF ALIPHATIC TERTIARY AMINO-GROUP N-SUBSTITUTED ACRYLAMIDES*

LI Fumian; WANG Lin; DING Yewei; FENG Xinde

Your Location：

Home >

Browse articles >

SYNTHESIS AND POLYMERIZATION OF ALIPHATIC TERTIARY AMINO-GROUP N-SUBSTITUTED ACRYLAMIDES*

Papers | Updated：2021-06-21

- SYNTHESIS AND POLYMERIZATION OF ALIPHATIC TERTIARY AMINO-GROUP N-SUBSTITUTED ACRYLAMIDES*
- SYNTHESIS AND POLYMERIZATION OF ALIPHATIC TERTIARY AMINO-GROUP N-SUBSTITUTED ACRYLAMIDES*
- 高分子科学（英文版） 1985年3卷第2期页码：140-149
- Affiliations：
- Author bio：
- Funds：
- DOI：
  中图分类号：
- 纸质出版：1985-06-20
- Accepted：
Scan QR Code
LI Fumian, WANG Lin, DING Yewei, 等. SYNTHESIS AND POLYMERIZATION OF ALIPHATIC TERTIARY AMINO-GROUP N-SUBSTITUTED ACRYLAMIDES*[J]. 高分子科学（英文版）, 1985,3(2):140-149.

LI Fumian, WANG Lin, DING Yewei, et al. SYNTHESIS AND POLYMERIZATION OF ALIPHATIC TERTIARY AMINO-GROUP N-SUBSTITUTED ACRYLAMIDES*[J]. 1985, 3(2): 140-149.
LI Fumian, WANG Lin, DING Yewei, 等. SYNTHESIS AND POLYMERIZATION OF ALIPHATIC TERTIARY AMINO-GROUP N-SUBSTITUTED ACRYLAMIDES*[J]. 高分子科学（英文版）, 1985,3(2):140-149. DOI：

LI Fumian, WANG Lin, DING Yewei, et al. SYNTHESIS AND POLYMERIZATION OF ALIPHATIC TERTIARY AMINO-GROUP N-SUBSTITUTED ACRYLAMIDES*[J]. 1985, 3(2): 140-149. DOI：

摘要

Aliphatic tertiary amino-group N-substituted acrylamides

N-acryl-N′-methylpiperazine (AMP)and N-methacryl-N′-methylpiperazine (MAMP) were synthesized directly from N-methylpiperazinewith corresponding acryloyl chlorides and characterized by elementary analysis of their picrates

1H-NMR

IR and MS. AMP did not polymerize with benzoyl peroxide (BPO)

but could poly-merize with lauroyl peroxide (LPO). The rate equation of the polymerization was given as RP=KP [AMP]1.5[LPO]0.5 and the overall activation energy of this polymerization system was 10.8Kcal/mol.The redox nature of LPO with the monomer itself was suggested.Even though AMP and MAMP hardly proceed the polymerization initiated with BPO

but under lower concentration would form redox system with BPO to initiate the polymerization of MMA readily.The rate equation of the polymerization of MMA initiated with MAMP-BPO system was given as Rp=Kp[MMA][MAMP]0.5[BPO]0.5 and the overall activation energy was 10.2 Kcal/mol.The analysis of the obtained polymers confirmed that MAMP not only initiated the polymerization of MMA by combining with BPO

but also took part in the polymer chains imparting them with better biocompatibility.

Abstract

Aliphatic tertiary amino-group N-substituted acrylamides

1H-NMR

IR and MS. AMP did not polymerize with benzoyl peroxide (BPO)

but also took part in the polymer chains imparting them with better biocompatibility.

关键词

Keywords

references

浏览量

Downloads

CSCD

文章被引用时，请邮件提醒。

Submit

工具集

关联资源

Enhanced Segment Mobility Promotes Stereocomplex Crystallization in Polymer Blends via Elevated Segmental Miscibility

Energy Storage Performance of Supercapacitors with Polyelectrolyte Surface Coatings: Effects of Dielectric Contrast

Sliding Dynamics of Ring Chain on a Rod-Coil Block Copolymer in Rotaxane

Multiple-Responsive Chiral Hydrogels from Helical Dendronized Poly(phenylacetylene)s

Special Topic: Chirality in Polymers