KINETIC STUDY OF GAS-PHASE POLYMERIZATION OF PROPENE BY THE INHIBITION METHOD USING CARBON MONOXIDE*

LI Yufei; TANG Shipei

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KINETIC STUDY OF GAS-PHASE POLYMERIZATION OF PROPENE BY THE INHIBITION METHOD USING CARBON MONOXIDE*

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- KINETIC STUDY OF GAS-PHASE POLYMERIZATION OF PROPENE BY THE INHIBITION METHOD USING CARBON MONOXIDE*
- KINETIC STUDY OF GAS-PHASE POLYMERIZATION OF PROPENE BY THE INHIBITION METHOD USING CARBON MONOXIDE*
- 高分子科学（英文版） 1985年3卷第1期页码：26-34
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- 纸质出版：1985-03-20
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LI Yufei, TANG Shipei. KINETIC STUDY OF GAS-PHASE POLYMERIZATION OF PROPENE BY THE INHIBITION METHOD USING CARBON MONOXIDE*[J]. 高分子科学（英文版）, 1985,3(1):26-34.

LI Yufei, TANG Shipei. KINETIC STUDY OF GAS-PHASE POLYMERIZATION OF PROPENE BY THE INHIBITION METHOD USING CARBON MONOXIDE*[J]. 1985, 3(1): 26-34.
LI Yufei, TANG Shipei. KINETIC STUDY OF GAS-PHASE POLYMERIZATION OF PROPENE BY THE INHIBITION METHOD USING CARBON MONOXIDE*[J]. 高分子科学（英文版）, 1985,3(1):26-34. DOI：

LI Yufei, TANG Shipei. KINETIC STUDY OF GAS-PHASE POLYMERIZATION OF PROPENE BY THE INHIBITION METHOD USING CARBON MONOXIDE*[J]. 1985, 3(1): 26-34. DOI：

摘要

The inhibition method using CO to determine the active center concentration C* in olefin poly-merization and the kinetics of gas-phase polymerization of propene were studied. The reliabilityof the method when used in gas-phase polymerization of propene is proved and the influencing fac-tor of the method is found to be the "repeating inhibition" of CO to the active centers. The C*

the rate constant kP and the activation energy were determined from the experimentalresults. We concluded that the C* decreases with polymerization time and coincides with the decay rate of the polymerization.

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