DECARBOXYLATION OF ALLYL β-KETO ESTERS TO UNSATURATED KETONES ON POLYMER BOUND PHOSPHINE-
PALLADIUM (0)COMPLEXES*

CHEN Bushi; WANG Dianxun; LIU Hanfan

Your Location：

Home >

Browse articles >

DECARBOXYLATION OF ALLYL β-KETO ESTERS TO UNSATURATED KETONES ON POLYMER BOUND PHOSPHINE- PALLADIUM (0)COMPLEXES*

Papers | Updated：2021-06-21

- DECARBOXYLATION OF ALLYL β-KETO ESTERS TO UNSATURATED KETONES ON POLYMER BOUND PHOSPHINE- PALLADIUM (0)COMPLEXES*
- DECARBOXYLATION OF ALLYL β-KETO ESTERS TO UNSATURATED KETONES ON POLYMER BOUND PHOSPHINE- PALLADIUM (0)COMPLEXES*
- 高分子科学（英文版） 1985年3卷第1期页码：48-55
- Affiliations：
- Author bio：
- Funds：
- DOI：
  中图分类号：
- 纸质出版：1985-03-20
- Accepted：
Scan QR Code
CHEN Bushi, WANG Dianxun, LIU Hanfan. DECARBOXYLATION OF ALLYL β-KETO ESTERS TO UNSATURATED KETONES ON POLYMER BOUND PHOSPHINE- PALLADIUM (0)COMPLEXES*[J]. 高分子科学（英文版）, 1985,3(1):48-55.

CHEN Bushi, WANG Dianxun, LIU Hanfan. DECARBOXYLATION OF ALLYL β-KETO ESTERS TO UNSATURATED KETONES ON POLYMER BOUND PHOSPHINE- PALLADIUM (0)COMPLEXES*[J]. 1985, 3(1): 48-55.
CHEN Bushi, WANG Dianxun, LIU Hanfan. DECARBOXYLATION OF ALLYL β-KETO ESTERS TO UNSATURATED KETONES ON POLYMER BOUND PHOSPHINE- PALLADIUM (0)COMPLEXES*[J]. 高分子科学（英文版）, 1985,3(1):48-55. DOI：

CHEN Bushi, WANG Dianxun, LIU Hanfan. DECARBOXYLATION OF ALLYL β-KETO ESTERS TO UNSATURATED KETONES ON POLYMER BOUND PHOSPHINE- PALLADIUM (0)COMPLEXES*[J]. 1985, 3(1): 48-55. DOI：

摘要

Polystyrylphosphine-Pd(0) and silica supported polysiloxane-phosphine-Pd(0) complexeswere synthesized and characterized. Their catalytic properties for the decarboxylation of allyl β-keto esters were investigated. It was found that these complexes have good catalytic activities undermild condition for this decarboxylation in which many novel unsaturated ketones were obtained.The selectivity of this catalytic decarboxylation depends on the polymer ligand and the P/Pd ratioof catalyst. The stabilities of polymer phosphine-Pd(0) complexes catalysts are better than their homogeneous analogue.

Abstract

关键词

Keywords

references

浏览量

Downloads

CSCD

文章被引用时，请邮件提醒。

Submit

工具集

关联资源

Preparation and Chiral Recognition Ability of Crystalline Cellulose Phenylcarbamate

pH-Responsive L-Cysteine-conjugated Polydopamine Nanocarriers for Controlled Release of Emamectin Benzoate against Pieris brassicae

Highly Regio- and trans-Selective Ring-opening Metathesis Polymerization of Chiral Aza-norbornene with a Simple Phenylimido-Tungsten Catalyst

End-to-End Neuron-inspired Signal Transduction Using Organic Electrochemical Transistors

Alternating Poly(ether-alt-ester)s with High Glass Transition Temperature Enabled by Rotationally Constrained Biaryl Units