CHARACTERIZATION OF COMPOSITIONAL HETEROGENEITY OF SEGMENTED COPOLYMERS BY GPC TECHNIQUE*
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CHARACTERIZATION OF COMPOSITIONAL HETEROGENEITY OF SEGMENTED COPOLYMERS BY GPC TECHNIQUE*
CHARACTERIZATION OF COMPOSITIONAL HETEROGENEITY OF SEGMENTED COPOLYMERS BY GPC TECHNIQUE*
高分子科学(英文版)1985年3卷第1期 页码:63-67
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纸质出版:1985-03-20
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XU Mao, YE Meiling, SHI Lianghe, 等. CHARACTERIZATION OF COMPOSITIONAL HETEROGENEITY OF SEGMENTED COPOLYMERS BY GPC TECHNIQUE*[J]. 高分子科学(英文版), 1985,3(1):63-67.
XU Mao, YE Meiling, SHI Lianghe, et al. CHARACTERIZATION OF COMPOSITIONAL HETEROGENEITY OF SEGMENTED COPOLYMERS BY GPC TECHNIQUE*[J]. 1985, 3(1): 63-67.
XU Mao, YE Meiling, SHI Lianghe, 等. CHARACTERIZATION OF COMPOSITIONAL HETEROGENEITY OF SEGMENTED COPOLYMERS BY GPC TECHNIQUE*[J]. 高分子科学(英文版), 1985,3(1):63-67.DOI:
XU Mao, YE Meiling, SHI Lianghe, et al. CHARACTERIZATION OF COMPOSITIONAL HETEROGENEITY OF SEGMENTED COPOLYMERS BY GPC TECHNIQUE*[J]. 1985, 3(1): 63-67.DOI:
CHARACTERIZATION OF COMPOSITIONAL HETEROGENEITY OF SEGMENTED COPOLYMERS BY GPC TECHNIQUE*
The GPC technique with two detectors has been used to study the heterogeneity in compositionthard segment content) of a series of polyethylene terephthalate/polycaprolactone segmented copoly-mers. Improvement in data treatment has been made to avoid the difficulty resulted from the lake of low molecular weight hard segment homopolymers. Results show that for each sample the moleculesof larger coil size in CHCI3 usually have higher hard segment content. A parameter
the average deviation of hard segment content
has been proposed to characterize the heterogeneity in composition of the samples.It is found that the heterogeneity of the samples increases with increasing their average hard segment content.
Abstract
The GPC technique with two detectors has been used to study the heterogeneity in compositionthard segment content) of a series of polyethylene terephthalate/polycaprolactone segmented copoly-mers. Improvement in data treatment has been made to avoid the difficulty resulted from the lake of low molecular weight hard segment homopolymers. Results show that for each sample the moleculesof larger coil size in CHCI3 usually have higher hard segment content. A parameter
the average deviation of hard segment content
has been proposed to characterize the heterogeneity in composition of the samples.It is found that the heterogeneity of the samples increases with increasing their average hard segment content.
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