STUDY ON THE SYNTHESIS OF POLYSTYRENESUPPORTED MACROCYCLIC MERCAPTAL CHELATING RESIN AND ITS PROPERTIES*
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STUDY ON THE SYNTHESIS OF POLYSTYRENESUPPORTED MACROCYCLIC MERCAPTAL CHELATING RESIN AND ITS PROPERTIES*
STUDY ON THE SYNTHESIS OF POLYSTYRENESUPPORTED MACROCYCLIC MERCAPTAL CHELATING RESIN AND ITS PROPERTIES*
高分子科学(英文版)1984年2卷第1期 页码:25-32
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纸质出版:1984-07-20
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SUN Qiang, ZHANG Jinlan, XU Jiping. STUDY ON THE SYNTHESIS OF POLYSTYRENESUPPORTED MACROCYCLIC MERCAPTAL CHELATING RESIN AND ITS PROPERTIES*[J]. 高分子科学(英文版), 1984,2(1):25-32.
SUN Qiang, ZHANG Jinlan, XU Jiping. STUDY ON THE SYNTHESIS OF POLYSTYRENESUPPORTED MACROCYCLIC MERCAPTAL CHELATING RESIN AND ITS PROPERTIES*[J]. 1984, 2(1): 25-32.
SUN Qiang, ZHANG Jinlan, XU Jiping. STUDY ON THE SYNTHESIS OF POLYSTYRENESUPPORTED MACROCYCLIC MERCAPTAL CHELATING RESIN AND ITS PROPERTIES*[J]. 高分子科学(英文版), 1984,2(1):25-32.DOI:
SUN Qiang, ZHANG Jinlan, XU Jiping. STUDY ON THE SYNTHESIS OF POLYSTYRENESUPPORTED MACROCYCLIC MERCAPTAL CHELATING RESIN AND ITS PROPERTIES*[J]. 1984, 2(1): 25-32.DOI:
STUDY ON THE SYNTHESIS OF POLYSTYRENESUPPORTED MACROCYCLIC MERCAPTAL CHELATING RESIN AND ITS PROPERTIES*
Chelating resin with macrocyclic mercaptal group supported on macroporous polystyrene beads was synthesized
which showed good selectivity to Hg2+: its complexing capacity amounted to 30—60 mg Hg2+/g resin
two orders of magnitude greater than for other metal ions such as Ca2+
Zn2+
Cd2+
Pb2+ etc. This resin could restore the activity of urease which had been deactivated by poisoning with Hg2+. Its restoring power was far better than that of the mercapto-resin and common anionic exchange resins.It showed some promising use as an oral polymeric detoxifying drug for mercury poisoning.
Abstract
Chelating resin with macrocyclic mercaptal group supported on macroporous polystyrene beads was synthesized
which showed good selectivity to Hg2+: its complexing capacity amounted to 30—60 mg Hg2+/g resin
two orders of magnitude greater than for other metal ions such as Ca2+
Zn2+
Cd2+
Pb2+ etc. This resin could restore the activity of urease which had been deactivated by poisoning with Hg2+. Its restoring power was far better than that of the mercapto-resin and common anionic exchange resins.It showed some promising use as an oral polymeric detoxifying drug for mercury poisoning.
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