KINETIC STUDIES ON THE POLYMERIZATION OF ACRYLONITRILE INITIATED BY METALLIC MAGNESIUM-NITRIC ACID SYSTEM

WU Chinyung

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KINETIC STUDIES ON THE POLYMERIZATION OF ACRYLONITRILE INITIATED BY METALLIC MAGNESIUM-NITRIC ACID SYSTEM

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- KINETIC STUDIES ON THE POLYMERIZATION OF ACRYLONITRILE INITIATED BY METALLIC MAGNESIUM-NITRIC ACID SYSTEM
- KINETIC STUDIES ON THE POLYMERIZATION OF ACRYLONITRILE INITIATED BY METALLIC MAGNESIUM-NITRIC ACID SYSTEM
- 高分子科学（英文版） 1983年1卷第2期页码：115-124
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- 纸质出版：1983-11-20
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WU Chinyung. KINETIC STUDIES ON THE POLYMERIZATION OF ACRYLONITRILE INITIATED BY METALLIC MAGNESIUM-NITRIC ACID SYSTEM[J]. 高分子科学（英文版）, 1983,1(2):115-124.

WU Chinyung. KINETIC STUDIES ON THE POLYMERIZATION OF ACRYLONITRILE INITIATED BY METALLIC MAGNESIUM-NITRIC ACID SYSTEM[J]. 1983, 1(2): 115-124.
WU Chinyung. KINETIC STUDIES ON THE POLYMERIZATION OF ACRYLONITRILE INITIATED BY METALLIC MAGNESIUM-NITRIC ACID SYSTEM[J]. 高分子科学（英文版）, 1983,1(2):115-124. DOI：

WU Chinyung. KINETIC STUDIES ON THE POLYMERIZATION OF ACRYLONITRILE INITIATED BY METALLIC MAGNESIUM-NITRIC ACID SYSTEM[J]. 1983, 1(2): 115-124. DOI：

摘要

This article reports the polymerization kinetics of acrylonitrile initiated by metallic magnesiumnitric acid system. The rate of polymerization is independent of the amount of magnesium used; when the concentration of nitric acid is higher than acrylonitrile

the equation of polymerization kinetics may be expressed asRp =1.91×105e-15000/RT[Mg]0[AN]2.2 [HNO3]0.45 The result of copolymerization of acyrlonitrile and methyl acrylate supports a free-radical mechanism.

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