A NEW PEAK (T4) IN THE 13C-NMR SPECTRUM OF POLYBUTADIENE

ZHOU Zinan; XIE Demin; ZHANG Jianguo; WU Qinyi; FENG Zhiliu

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A NEW PEAK (T4) IN THE 13C-NMR SPECTRUM OF POLYBUTADIENE

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- A NEW PEAK (T4) IN THE 13C-NMR SPECTRUM OF POLYBUTADIENE
- A NEW PEAK (T4) IN THE 13C-NMR SPECTRUM OF POLYBUTADIENE
- 高分子科学（英文版） 1983年1卷第1期页码：80-82
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ZHOU Zinan, XIE Demin, ZHANG Jianguo, 等. A NEW PEAK (T4) IN THE 13C-NMR SPECTRUM OF POLYBUTADIENE[J]. 高分子科学（英文版）, 1983,1(1):80-82.

ZHOU Zinan, XIE Demin, ZHANG Jianguo, et al. A NEW PEAK (T4) IN THE 13C-NMR SPECTRUM OF POLYBUTADIENE[J]. 1983,1(1):80-82.
ZHOU Zinan, XIE Demin, ZHANG Jianguo, 等. A NEW PEAK (T4) IN THE 13C-NMR SPECTRUM OF POLYBUTADIENE[J]. 高分子科学（英文版）, 1983,1(1):80-82. DOI：

ZHOU Zinan, XIE Demin, ZHANG Jianguo, et al. A NEW PEAK (T4) IN THE 13C-NMR SPECTRUM OF POLYBUTADIENE[J]. 1983,1(1):80-82. DOI：

摘要

A new peak at 39.0 ppm in the 13C-NMR spectrum of polybutadiene (PBD) was discovered. This peak is assigned to the fourth peak (T4) of trans-1,4-sequence marked with an asterisk as shown in Fig. 3 in the text.The occurrence of T4 carbon nuclei is strongly affected by their neighboring 1,2-units. So long as both contents of trans-1,4- and 1,2-units attain their proper amounts the peak (T4) with appear in the 13C-NMR spectrum of PBD.

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