POLYMERIZATION OF (METH)ACRYLATES WITH ALUMINUM-BASED INITIATORS

Yan-guo Li; Jing-yu Liu; Yue-sheng Li

Your Location：

Home >

Browse articles >

POLYMERIZATION OF (METH)ACRYLATES WITH ALUMINUM-BASED INITIATORS

Papers | Updated：2021-06-21

- POLYMERIZATION OF (METH)ACRYLATES WITH ALUMINUM-BASED INITIATORS
- POLYMERIZATION OF (METH)ACRYLATES WITH ALUMINUM-BASED INITIATORS
- 高分子科学（英文版） 2010年28卷第1期页码：101-106
- Affiliations：
- Author bio：
- Funds：
- DOI：
  中图分类号：
- 纸质出版：2010-01-20
- Accepted：
Scan QR Code
Yan-guo Li, Jing-yu Liu, Yue-sheng Li. POLYMERIZATION OF (METH)ACRYLATES WITH ALUMINUM-BASED INITIATORS[J]. 高分子科学（英文版）, 2010,28(1):101-106.

Yan-guo Li, Jing-yu Liu, Yue-sheng Li. POLYMERIZATION OF (METH)ACRYLATES WITH ALUMINUM-BASED INITIATORS[J]. 2010, 28(1): 101-106.
Yan-guo Li, Jing-yu Liu, Yue-sheng Li. POLYMERIZATION OF (METH)ACRYLATES WITH ALUMINUM-BASED INITIATORS[J]. 高分子科学（英文版）, 2010,28(1):101-106. DOI：

Yan-guo Li, Jing-yu Liu, Yue-sheng Li. POLYMERIZATION OF (METH)ACRYLATES WITH ALUMINUM-BASED INITIATORS[J]. 2010, 28(1): 101-106. DOI：

摘要

A simple and effective way to prepare poly(acrylate)s

such as poly(methacrylate)

poly(butyl acrylate) and poly(butyl methacrylate)

has been achieved by using the single component aluminum-based compounds

such as modified methylaluminoxane (MMAO)

triisobutylaluminium (TIBA) and triethylaluminium (TEA) as initiators. Effective initiations and high molecular weight polymers with unimodal molecular weight distributions could be easily obtained by varying the reaction parameters of systems under mild conditions. Although these aluminum compounds were inefficient initiators for methyl methacrylate (MMA) polymerization

they exhibited remarkable catalytic activity for butyl methacrylate (BMA) polymerization

affording high molecular weight poly(BMA)s.

Abstract

A simple and effective way to prepare poly(acrylate)s

such as poly(methacrylate)

poly(butyl acrylate) and poly(butyl methacrylate)

has been achieved by using the single component aluminum-based compounds

such as modified methylaluminoxane (MMAO)

they exhibited remarkable catalytic activity for butyl methacrylate (BMA) polymerization

affording high molecular weight poly(BMA)s.

关键词

Keywords

references

浏览量

110

Downloads

CSCD

文章被引用时，请邮件提醒。

Submit

工具集

关联资源

pH-Responsive L-Cysteine-conjugated Polydopamine Nanocarriers for Controlled Release of Emamectin Benzoate against Pieris brassicae

A Paradigm for BF3 Co-initiated Cationic Polymerization with Low Dispersity: Introducing Acetonitrile and Lowering the Reaction Temperature

Upgrading Commercially Available Polyethylene to High-value Materials with Strong Mechanical Performance and Hydrophilicity by Blending with Ethylene/meta-Methoxystyrene Copolymers

Experimental Investigation of Graphene and TiO2 Reinforced Poly(vinyl alcohol)-based Fiber Metal Laminates

Optically Active Helical Poly(phenyl isocyanide)s Bearing Achiral Benzanilide Pendants: from Controlled Synthesis to Enantioseparation Application