ULTRAFILTRATION MEMBRANE FORMATION OF PES-C, PES AND PPESK POLYMERS WITH DIFFERENT SOLVENTS
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ULTRAFILTRATION MEMBRANE FORMATION OF PES-C, PES AND PPESK POLYMERS WITH DIFFERENT SOLVENTS
ULTRAFILTRATION MEMBRANE FORMATION OF PES-C, PES AND PPESK POLYMERS WITH DIFFERENT SOLVENTS
高分子科学(英文版)2009年27卷第2期 页码:165-172
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纸质出版:2009-03-20
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Wei-na Sun, Cui-xian Chen, Ji-ding Li, 等. ULTRAFILTRATION MEMBRANE FORMATION OF PES-C, PES AND PPESK POLYMERS WITH DIFFERENT SOLVENTS[J]. 高分子科学(英文版), 2009,27(2):165-172.
Wei-na Sun, Cui-xian Chen, Ji-ding Li, et al. ULTRAFILTRATION MEMBRANE FORMATION OF PES-C, PES AND PPESK POLYMERS WITH DIFFERENT SOLVENTS[J]. 2009, 27(2): 165-172.
Wei-na Sun, Cui-xian Chen, Ji-ding Li, 等. ULTRAFILTRATION MEMBRANE FORMATION OF PES-C, PES AND PPESK POLYMERS WITH DIFFERENT SOLVENTS[J]. 高分子科学(英文版), 2009,27(2):165-172.DOI:
Wei-na Sun, Cui-xian Chen, Ji-ding Li, et al. ULTRAFILTRATION MEMBRANE FORMATION OF PES-C, PES AND PPESK POLYMERS WITH DIFFERENT SOLVENTS[J]. 2009, 27(2): 165-172.DOI:
ULTRAFILTRATION MEMBRANE FORMATION OF PES-C, PES AND PPESK POLYMERS WITH DIFFERENT SOLVENTS
Ultrafiltration membranes were prepared using phenolphthalein polyarylethersulfone (PES-C)
polyethersulfone (PES) and poly(phthalazinone ether sulfone ketone) (PPESK) as polymers and NMP
DMAc
DMF and DMSO as solvents by immersion precipitation via phase inversion. Experimental data of thermodynamic properties of the polymer solutions and kinetic process of membrane formation were reported. For polymer solutions with good solvents
the sequence of the viscous flow activation energy (Eη) was coincident with that of the viscosity (η)
without depending on the dissolving power of the solvents (characterized by intrinsic viscosity ([η])). The cloud point of the dilute polymer solutions was related to [η] of the polymer and gave a strong influence on the gelation rate in membrane formation process. The pure water flux (J) and the bovine serum albumin (BSA) rejection (R) of PES-C
PES and PPESK membranes were measured
the pure water flux (J) of membranes significantly depended on the gelation rate. The open porosity (OP) and the maximum pore size of membrane surface were calculated
and the relationship between membrane performance and membrane pore structure was discussed.
Abstract
Ultrafiltration membranes were prepared using phenolphthalein polyarylethersulfone (PES-C)
polyethersulfone (PES) and poly(phthalazinone ether sulfone ketone) (PPESK) as polymers and NMP
DMAc
DMF and DMSO as solvents by immersion precipitation via phase inversion. Experimental data of thermodynamic properties of the polymer solutions and kinetic process of membrane formation were reported. For polymer solutions with good solvents
the sequence of the viscous flow activation energy (Eη) was coincident with that of the viscosity (η)
without depending on the dissolving power of the solvents (characterized by intrinsic viscosity ([η])). The cloud point of the dilute polymer solutions was related to [η] of the polymer and gave a strong influence on the gelation rate in membrane formation process. The pure water flux (J) and the bovine serum albumin (BSA) rejection (R) of PES-C
PES and PPESK membranes were measured
the pure water flux (J) of membranes significantly depended on the gelation rate. The open porosity (OP) and the maximum pore size of membrane surface were calculated
and the relationship between membrane performance and membrane pore structure was discussed.
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