SELF ASSEMBLY OF ABC TRIBLOCK COPOLYMER THIN FILMS ON A BRUSH-COATED SUBSTRATE
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SELF ASSEMBLY OF ABC TRIBLOCK COPOLYMER THIN FILMS ON A BRUSH-COATED SUBSTRATE
SELF ASSEMBLY OF ABC TRIBLOCK COPOLYMER THIN FILMS ON A BRUSH-COATED SUBSTRATE
高分子科学(英文版)2009年27卷第4期 页码:583-592
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纸质出版:2009-07-20
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Zhi-bin Jiang, Rong Wang, Gi Xue. SELF ASSEMBLY OF ABC TRIBLOCK COPOLYMER THIN FILMS ON A BRUSH-COATED SUBSTRATE[J]. 高分子科学(英文版), 2009,27(4):583-592.
Zhi-bin Jiang, Rong Wang, Gi Xue. SELF ASSEMBLY OF ABC TRIBLOCK COPOLYMER THIN FILMS ON A BRUSH-COATED SUBSTRATE[J]. 2009, 27(4): 583-592.
Zhi-bin Jiang, Rong Wang, Gi Xue. SELF ASSEMBLY OF ABC TRIBLOCK COPOLYMER THIN FILMS ON A BRUSH-COATED SUBSTRATE[J]. 高分子科学(英文版), 2009,27(4):583-592.DOI:
Zhi-bin Jiang, Rong Wang, Gi Xue. SELF ASSEMBLY OF ABC TRIBLOCK COPOLYMER THIN FILMS ON A BRUSH-COATED SUBSTRATE[J]. 2009, 27(4): 583-592.DOI:
SELF ASSEMBLY OF ABC TRIBLOCK COPOLYMER THIN FILMS ON A BRUSH-COATED SUBSTRATE
Self assemblies of ABC triblock copolymer thin films on a densely brush-coated substrate were investigated by using the self-consistent field theory. The middle block B and the coated polymer form one phase and the alternating phase A and phase C occur when the film is very thin either for the neutral or selective hard surface (which is opposite to the brush-coated substrate). The lamellar phase is stable on the hard surface when it is neutral and interestingly
the short block tends to stay on this hard surface. The rippled structure forms when the cylindrical phase exists near the surface between grafted polymers and ABC block copolymers. Due to the existence of the hydrophilic brush-coated surface serving as a soft surface of the film
the energy fluctuation existing in the film confined by two hard surfaces disappears. The results are helpful for designing the nanopattern of the film and realizing the functional thin film
such as adding the functional short block A to the BC diblock copolymer.
Abstract
Self assemblies of ABC triblock copolymer thin films on a densely brush-coated substrate were investigated by using the self-consistent field theory. The middle block B and the coated polymer form one phase and the alternating phase A and phase C occur when the film is very thin either for the neutral or selective hard surface (which is opposite to the brush-coated substrate). The lamellar phase is stable on the hard surface when it is neutral and interestingly
the short block tends to stay on this hard surface. The rippled structure forms when the cylindrical phase exists near the surface between grafted polymers and ABC block copolymers. Due to the existence of the hydrophilic brush-coated surface serving as a soft surface of the film
the energy fluctuation existing in the film confined by two hard surfaces disappears. The results are helpful for designing the nanopattern of the film and realizing the functional thin film
such as adding the functional short block A to the BC diblock copolymer.
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