STUDIES ON SELF-ASSOCIATIVE BEHAVIOR OF A NOVEL CATION AMPHIPHILIC POLYMER

Jing Li a; Fei-peng Wu a; Er-jian Wang a

Your Location：

Home >

Browse articles >

STUDIES ON SELF-ASSOCIATIVE BEHAVIOR OF A NOVEL CATION AMPHIPHILIC POLYMER

Note | Updated：2021-06-21

- STUDIES ON SELF-ASSOCIATIVE BEHAVIOR OF A NOVEL CATION AMPHIPHILIC POLYMER
- STUDIES ON SELF-ASSOCIATIVE BEHAVIOR OF A NOVEL CATION AMPHIPHILIC POLYMER
- 高分子科学（英文版） 2009年27卷第4期页码：593-596
- Affiliations：
- Author bio：
- Funds：
- DOI：
  中图分类号：
- 纸质出版：2009-07-20
- Accepted：
Scan QR Code
Jing Li a, Fei-peng Wu a, Er-jian Wang a. STUDIES ON SELF-ASSOCIATIVE BEHAVIOR OF A NOVEL CATION AMPHIPHILIC POLYMER[J]. 高分子科学（英文版）, 2009,27(4):593-596.

Jing Li a, b, Fei-peng Wu a. STUDIES ON SELF-ASSOCIATIVE BEHAVIOR OF A NOVEL CATION AMPHIPHILIC POLYMER[J]. 2009, 27(4): 593-596.
Jing Li a, Fei-peng Wu a, Er-jian Wang a. STUDIES ON SELF-ASSOCIATIVE BEHAVIOR OF A NOVEL CATION AMPHIPHILIC POLYMER[J]. 高分子科学（英文版）, 2009,27(4):593-596. DOI：

Jing Li a, b, Fei-peng Wu a. STUDIES ON SELF-ASSOCIATIVE BEHAVIOR OF A NOVEL CATION AMPHIPHILIC POLYMER[J]. 2009, 27(4): 593-596. DOI：

摘要

A novel associating polymer P(AEBA) was synthesized by radical polymerization of the cationic amphiphilic monomer

4-(2-(acryloyloxy)ethoxy)benzyl tri-ethyl ammonium bromide (AEBA)

in aqueous solutions. P(AEBA) displays a strong tendency for self-association in aqueous solutions and is sensitive to the external stimulation such as added salt. The associative properties and morphologies of P(AEBA) were studied by fluorescnece probe technique

viscometry and TEM. In dilute salt-free solutions P(AEBA) behaves as polyelectrolyte

while its behavior is similar to that of the polysoap as salt added. Accompanying increasing polymer concentration

polymer aggregation conformation changes from an extended necklace-like structure to a compact globular aggregate corresponding to the viscosity reduction.

Abstract

A novel associating polymer P(AEBA) was synthesized by radical polymerization of the cationic amphiphilic monomer

4-(2-(acryloyloxy)ethoxy)benzyl tri-ethyl ammonium bromide (AEBA)

viscometry and TEM. In dilute salt-free solutions P(AEBA) behaves as polyelectrolyte

while its behavior is similar to that of the polysoap as salt added. Accompanying increasing polymer concentration

polymer aggregation conformation changes from an extended necklace-like structure to a compact globular aggregate corresponding to the viscosity reduction.

关键词

Keywords

references

浏览量

119

Downloads

CSCD

文章被引用时，请邮件提醒。

Submit

工具集

关联资源

Squaramide-directed Cooperative One-dimensional Assembly in Telechelic Polydimethylsiloxane for Hierarchical Network Formation

End-group and Side-chain Dual-engineering of Selenium-fused Acceptors for 20.08% Efficiency Polymer Solar Cells with Low Energy Loss

Highly Regio- and trans-Selective Ring-opening Metathesis Polymerization of Chiral Aza-norbornene with a Simple Phenylimido-Tungsten Catalyst

2026-9 Contents

A Paradigm for BF3 Co-initiated Cationic Polymerization with Low Dispersity: Introducing Acetonitrile and Lowering the Reaction Temperature