POSS-NEODYMIUM COMPLEX {[(i-C4H9)7(Si7O12)Nd]4NaCl} AS PRECURSOR FOR POLYMERIZATION OF ISOPRENE

Jian-fang Yu; Guang-ming Wu; Jing Huang; Wei-lin Sun; Zhi-quan Shen

Your Location：

Home >

Browse articles >

POSS-NEODYMIUM COMPLEX {[(i-C4H9)7(Si7O12)Nd]4NaCl} AS PRECURSOR FOR POLYMERIZATION OF ISOPRENE

Note | Updated：2021-06-21

- POSS-NEODYMIUM COMPLEX {[(i-C4H9)7(Si7O12)Nd]4NaCl} AS PRECURSOR FOR POLYMERIZATION OF ISOPRENE
- POSS-NEODYMIUM COMPLEX {[(i-C4H9)7(Si7O12)Nd]4NaCl} AS PRECURSOR FOR POLYMERIZATION OF ISOPRENE
- 高分子科学（英文版） 2009年27卷第4期页码：597-600
- Affiliations：
- Author bio：
- Funds：
- DOI：
  中图分类号：
Scan for full text
Jian-fang Yu, Guang-ming Wu, Jing Huang, 等. POSS-NEODYMIUM COMPLEX {[(i-C4H9)7(Si7O12)Nd]4NaCl} AS PRECURSOR FOR POLYMERIZATION OF ISOPRENE[J]. 高分子科学（英文版）, 2009,27(4):597-600.

Jian-fang Yu, Guang-ming Wu, Jing Huang, et al. POSS-NEODYMIUM COMPLEX {[(i-C4H9)7(Si7O12)Nd]4NaCl} AS PRECURSOR FOR POLYMERIZATION OF ISOPRENE[J]. 2009,27(4):597-600.
Jian-fang Yu, Guang-ming Wu, Jing Huang, 等. POSS-NEODYMIUM COMPLEX {[(i-C4H9)7(Si7O12)Nd]4NaCl} AS PRECURSOR FOR POLYMERIZATION OF ISOPRENE[J]. 高分子科学（英文版）, 2009,27(4):597-600. DOI：

Jian-fang Yu, Guang-ming Wu, Jing Huang, et al. POSS-NEODYMIUM COMPLEX {[(i-C4H9)7(Si7O12)Nd]4NaCl} AS PRECURSOR FOR POLYMERIZATION OF ISOPRENE[J]. 2009,27(4):597-600. DOI：

摘要

The tetrameric neodymium-silsesquioxane cage complex, {[(i-C4H9)7(Si7O12)Nd]4NaCl}, was prepared and used as precursor for the polymerization of isoprene. When activated by AlEt3 in the presence of TMSCl, this POSS-Nd complex (POSS = polyhedral oligomeric silsesquioxane) shows a moderate activity for the polymerization, and the effects of different ratios of Al/Nd, Cl/Nd and time on the polymerization were investigated. Moreover, The POSS-Nd complex may serve as models for the silica-supported rare earth catalyst, and a simplified surface model was also proposed.

Abstract

关键词

Keywords

references

浏览量

Downloads

CSCD

文章被引用时，请邮件提醒。

Submit

工具集

关联资源

暂无数据