School of Materials Science and Engineering, State key Laboratory of Advanced Materials for Intelligent Sensing, Tianjin Key Laboratory of Molecular Optoelectronic Sciences, Key Laboratory of Organic Integrated Circuits, Ministry of Education, Collaborative Innovation Center of Chemical Science and Engineering, Tianjin University, Tianjin 300072 China
yelong@tju.edu.cn
收稿:2025-12-29,
修回:2026-02-01,
录用:2026-02-26,
网络首发:2026-05-07,
纸质出版:2026-07-05
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Feng, J. T.; Ye, L. Advancing the thin-film mechanics of conjugated polymers: characterization, modulation, and innovation. Chinese J. Polym. Sci. 2026, 44, 2086–2111
Jin-Tao Feng, Long Ye. Advancing the Thin-film Mechanics of Conjugated Polymers: Characterization, Modulation, and Innovation[J]. Chinese Journal of Polymer Science, 2026, 44(7): 2086-2111.
Feng, J. T.; Ye, L. Advancing the thin-film mechanics of conjugated polymers: characterization, modulation, and innovation. Chinese J. Polym. Sci. 2026, 44, 2086–2111 DOI: 10.1007/s10118-026-3635-4.
Jin-Tao Feng, Long Ye. Advancing the Thin-film Mechanics of Conjugated Polymers: Characterization, Modulation, and Innovation[J]. Chinese Journal of Polymer Science, 2026, 44(7): 2086-2111. DOI: 10.1007/s10118-026-3635-4.
This review establishes a tripartite framework for conjugated polymer mechanics
spanning multiscale characterization
molecular and morphological engineering
and architectural innovation toward tailored functionality and bio-integrated electronics.
Conjugated polymer thin films are key functional layers in flexible and wearable devices
where mechanical behavior directly influences device performance and stability. However
accurate mechanical characterization remains challenging due to their nanoscale thickness and brittleness. This review aims to offer a holistic view on thin-film mechanics of conjugated polymers and systematically summarizes static and dynamic mechanical characterization methods for conjugated polymer thin films
spanning bulk materials
substrate-supported ultrathin films
and freestanding ultrathin films
and elucidates the measurement principles and key features of each technique. By integrating reported experimental results
we identify multiple factors affecting thin-film mechanical behavior. Finally
an outlook is presented in which
guided by device-level mechanical requirements
the mechanical behavior of polymer optoelectronic thin films is designed and regulated through multiple strategies
and comprehensively evaluated using complementary mechanical characterization approaches
enabling subsequent optimization based on the measured mechanical response.
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