State Key Laboratory of Advanced Fiber Materials, College of Materials Science and Engineering, Donghua University, Shanghai 201620, China
wlyu@dhu.edu.cn (W.L.)
yzliao@dhu.edu.cn (Y.Z.L.)
收稿:2025-12-23,
修回:2026-02-06,
录用:2026-02-14,
网络首发:2026-06-22,
纸质出版:2026-07-05
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Gong, X. Q.; Zhang, X. Z. Y.; Zhou, Y. F.; Shi, Y.; Zhang, Y. M.; Hu, J. W.; Li, P. C.; Lyu, W.; Liao, Y. Z. Hypercrosslinked porous organic polymers from tetraaniline and anthraquinone for high-capacitance, long-life supercapacitors. Chinese J. Polym. Sci. 2026, 44, 2212–2225
Xiao-Qian Gong, Xin-Ze-Yu Zhang, Yi-Fei Zhou, et al. Hypercrosslinked Porous Organic Polymers from Tetraaniline and Anthraquinone for High-capacitance, Long-life Supercapacitors[J]. Chinese Journal of Polymer Science, 2026, 44(7): 2212-2225.
Gong, X. Q.; Zhang, X. Z. Y.; Zhou, Y. F.; Shi, Y.; Zhang, Y. M.; Hu, J. W.; Li, P. C.; Lyu, W.; Liao, Y. Z. Hypercrosslinked porous organic polymers from tetraaniline and anthraquinone for high-capacitance, long-life supercapacitors. Chinese J. Polym. Sci. 2026, 44, 2212–2225 DOI: 10.1007/s10118-026-3623-8.
Xiao-Qian Gong, Xin-Ze-Yu Zhang, Yi-Fei Zhou, et al. Hypercrosslinked Porous Organic Polymers from Tetraaniline and Anthraquinone for High-capacitance, Long-life Supercapacitors[J]. Chinese Journal of Polymer Science, 2026, 44(7): 2212-2225. DOI: 10.1007/s10118-026-3623-8.
A redox-active hypercrosslinked polymer integrating tetraaniline and anthraquinone enables high-capacitance and long-life supercapacitors by constructing a hierarchical porous architecture with high-density redox-active sites.
Hypercrosslinked polymers (HCPs) are promising electrode materials for supercapacitors owing to their rigid three-dimensional networks and excellent structural stability; however
their electrochemical performance is often limited by an over-reliance on electric double-layer capacitance or insufficient redox-active sites. Herein
we report a series of hypercrosslinked polymers (HCPs) constructed from tetraaniline (TANI) and 2
6-diaminoanthraquinone (DAQ) to integrate abundant redox-active sites with robust three-dimensional porous networks for high-capacitance and long-life supercapacitor electrodes. By tuning the TANI-to-DAQ molar ratio
the optimized TADA11-HCP exhibits a hierarchical micro-/mesoporous architecture for exposed active sites and facilitated mass diffusion
along with the lowest optical bandgap (acid-treated) among the series for fast electron transport. Benefiting from the combined advantages of structural strength
hierarchical porosity
and an optimized electronic structure
TADA11-HCP achieves 700 F·g
−1
at 1 A·g
−1
and retains 92% capacitance after 10000 cycles
demonstrating excellent cycling stability. A flexible quasi-solid-state symmetric supercapacitor further demonstrates 278.4 F·g
−1
and an energy density of 38.7 Wh·kg
−1
highlighting the practical potential of TADA-HCPs for advanced supercapacitor applications. This work demonstrates an effective molecular-level strategy to enhance the capacitance of HCP-based electrodes while
maintaining long-term stability
providing insights into the rational design of high-performance HCPs for supercapacitor applications.
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